This work is intended to underline how the most-advanced experimental and theoretical
physical chemistry tools must be used synergistically to understand the reactivity of Ti …

Empty spaces are abhorred by nature, which immediately rushes in to fill the void. Humans
have learnt pretty well how to make ordered empty nanocontainers, and to get useful …

A thorough investigation of the active titanium species in TS‐1 zeolite was conducted by in
situ UV resonance Raman spectroscopy combined with UV/Vis diffuse reflectance …

One-step direct hydroxylation of aromatics is an atom-economic way for phenols production.
Ti-containing MFI zeolite is considered to be one of the most potential catalysts for …

Anatase TiO2 prepared by a simple sol–gel reaction of Ti (i-pro) 4 was studied as an early
transition metal oxide with Lewis acid sites workable in water. Fourier transform infrared (FT …

The siting of Ti, Sn, and Zr framework heteroatoms in zeolite BEA and the resulting Lewis
acidity were systematically investigated by periodic density functional theory (DFT) …

The epoxidation of allylic alcohols with H2O2 catalyzed by the hybrid [α-B-SbW9O33 (t
BuSiO) 3Ti (OiPr)] 3–(1) anion as a molecular model of heterogeneous Ti-silicalite TS-1 …

The elastic behaviour and the structural evolution of microporous materials compressed
hydrostatically in a pressure-transmitting fluid are drastically affected by the potential crystal …

Density functional theory (DFT) calculations were performed to investigate propylene
epoxidation mechanisms with H 2 O 2 over various TS-1 models in terms of active site …

The Lewis acidity of phosphate-immobilized anatase TiO 2 (phosphate/TiO 2) has been
studied to develop novel environmentally benign reaction systems. Fourier transform …