We report a versatile and functional-group-tolerant method for the Pd-catalyzed C–N cross-
coupling of five-membered heteroaryl halides with primary and secondary amines, an …

N-heterocyclic carbene (NHC) ligands have evolved from being simple lab curiosities to
tertiary phosphine mimics to finally take center stage as unique supporting ligands in …

Using the robust N-heterocyclic carbene–palladium complex (SIPr) Ph2Pd (cin) Cl, a highly
efficient and easy-to-operate method has been developed at room temperature for the …

Amination reactions play a pivotal role in synthetic organic chemistry, facilitating the
generation of nitrogen-containing scaffolds with broad applications in drug synthesis …

Xanthines, such as caffeine and theophylline, are abundant natural products that are often
present in foods. Leveraging renewable and benign resources for ligand design in …

C-Amino-1, 2, 4-triazoles are challenging polynitrogen substrates for metal-catalyzed
arylation due to their multidentate character, enhanced coordinating ability and decreased …

A visible-light-driven Mn-catalyzed C (sp3)–H amidation of diphenylmethane derivatives
with dioxazolones was described. These reactions occur with an external photosensitizer …

The increasing number of examples on cooperative dual catalysis involving organocatalysts
and transition metal catalysts indicate their wider acceptance and utility in synthetic …

Conjugated diyne derivatives are important scaffolds in modern organic synthetic chemistry.
Using the Glaser reaction involves the coupling of terminal alkynes which can efficiently …

Synthesis of α-branched aryl amines is a continuing challenge in synthetic and medicinal
chemistry. Although transition-metal-promoted C–N cross-coupling is a desirable approach …