Recent strategies in the nucleophilic dearomatization of pyridines, quinolines, and isoquinolines

M Escolano, D Gaviña, G Alzuet-Piña… - Chemical …, 2024 - ACS Publications
Dearomatization reactions have become fundamental chemical transformations in organic
synthesis since they allow for the generation of three-dimensional complexity from two …

Recent advances in organic reactions involving elemental sulfur

TB Nguyen - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
Elemental sulfur has been known since Antiquity and found widespread applications in the
preparation of black gunpowder, the synthesis of sulfuric acid as well as other sulfur …

The chemistry of heterocycles in the 21st century

VN Charushin, EV Verbitskiy, ON Chupakhin… - Uspekhi Khimii, 2024 - mathnet.ru
The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …

Copper-catalyzed decarboxylative cascade cyclization of propargylic cyclic carbonates/carbamates with pyridinium 1, 4-zwitterionic thiolates to fused polyheterocyclic …

TT Li, Y You, TJ Sun, YP Zhang, JQ Zhao… - Organic …, 2022 - ACS Publications
A copper-catalyzed decarboxylative cascade cyclization of propargylic cyclic carbonates/
carbamates with pyridinium 1, 4-zwitterionic thiolates is developed. A range of fused …

Indolizine Synthesis through Annulation of Pyridinium 1, 4‐Thiolates and Copper Carbenes: A Predictive Catalysis Approach

R Monreal‐Corona, À Díaz‐Jiménez… - Advanced Synthesis …, 2023 - Wiley Online Library
Predictive catalysis was applied to the reaction of pyridinium 1, 4‐zwitterionic thiolates with a
copper carbene. Theoretical calculations were first performed to determine the suitability of …

Synthesis of tetrasubstituted thiophenes via a [3+ 2] cascade cyclization reaction of pyridinium 1, 4-zwitterionic thiolates and activated allenes

S Zhai, X Zhang, B Cheng, H Li, Y Li, Y He… - Chemical …, 2020 - pubs.rsc.org
Synthesis of tetrasubstituted thiophenes via a [3+2] cascade cyclization reaction of pyridinium
1,4-zwitterionic thiolates and activated allenes - Chemical Communications (RSC Publishing) …

Synthesis of 5‐Trifluoromethylpyrroles from Heating‐Induced Annulation of Pyridinium 1,4‐Zwitterionic Thiolates with CF3‐Imidoyl Sulfoxonium Ylides

S Ling, Y Zhang, Z Chen, XF Wu - Advanced Synthesis & …, 2023 - Wiley Online Library
A heating‐induced desulfuration annulation of pyridinium 1, 4‐zwitterionic thiolates and CF3‐
substituted imidoyl sulfoxonium ylides has been achieved, allowing a route to biologically …

Recent advances in the cyclization reactions of pyridinium 1, n-zwitterions (n= 4 and 5): scope and mechanism

J Huang, L Zhang, X Meng - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Nitrogen-and sulfur-containing heterocyclic compounds widely exist in bioactive natural
products and drug molecules with unique bioactivity. In the past few decades, great efforts …

Copper (I) Iodide Catalyzed [3+ 3] Annulation of Iodonium Ylides with Pyridinium 1, 4-Zwitterionic Thiolates for the Synthesis of 1, 4-Oxathiin Scaffolds

À Díaz-Jiménez, SCD Kennington, A Roglans… - Organic …, 2023 - ACS Publications
The selective assembly of the 1, 4-oxathiin nucleus has been treated as a powerful strategy
to access this scaffold present in molecules with very interesting properties. In this study, the …

Application of pyridinium 1, 4-zwitterionic thiolates: Synthesis of benzopyridothiazepines and benzothiophenes

B Cheng, Y Li, T Wang, X Zhang, H Li… - The Journal of …, 2020 - ACS Publications
Pyridinium 1, 4-zwitterionic thiolates, as a novel kind of sulfur-containing synthon, have been
applied to the synthesis of 12a H-benzo [f] pyrido [1, 2-d][1, 4] thiazepines and benzo [b] …