Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

The reaction of readily available TEMPONa with aryl diazonium salts allows for clean
generation of the corresponding aryl radicals along with TEMPO. Aryl radical addition to …

The intramolecular cyclohexylene-bridged P/B frustrated Lewis pair [Mes2P C6H10 B
(C6F5) 2] 1b reacts rapidly with NO to give the persistent FLP-NO aminoxyl radical 2b …

1. INTRODUCTION For more than two decades, from the 1960s to the mid-1980s,
fundamental research in radical chemistry aroused tremedeous interest in the physical …

High-level ab initio molecular orbital theory calculations are used to identify the origin of the
remarkably high inhibition stoichiometric factors exhibited by dialkylamine-based radical …

In recent decades, quantum chemical calculations (QCC) have increased in accuracy, not
only providing the ranking of chemical reactivities and energy barriers (eg, for optimal …

The nitroxides of 7-azadispiro [5.1. 5.2] pentadecane and 7-azadispiro [5.1. 5.2] pentadeca-
14-ene series have been prepared, including thiol-specific methane thiosulfonate spin label …

Nitroxide‐mediated polymerization (NMP) is one of the most powerful reversible
deactivation radical polymerization techniques and has incredibly gained in maturity and …

Activation and deactivation Arrhenius parameters are estimated for nitroxide mediated
polymerization (NMP) of styrene initiated by BlocBuilder MA, based on an extensive set of …