For more than three decades, the ability of a fluorine atom involved in a C–F bond to act as a
hydrogen-bond acceptor has been a controversial issue. Throughout the years, more and …

The combined utility of many one and two dimensional NMR methodologies and DFT-based
theoretical calculations have been exploited to detect the intramolecular hydrogen bond …

Sulfur-containing polymers have been widely studied because of their high refractivity and
low dispersion, but the efficient synthetic approach of them is quite limited. In this work, we …

It is known that strong hydrogen‐bonding interactions play an important role in many
chemical and biological systems. However, weak or very weak hydrogen bonds, which are …

High-performance polymer electrolytes are desirable for developing solid-state lithium (Li)
metal batteries (SSLMBs) with enhanced safety and high energy density; however, their …

Using the principle that constrained conformational spaces can generate novel and hidden
molecular properties, we challenged the commonly held perception that a single-centered …

The primary objective of atomic-scale simulations is to meticulously monitor the formation
and evolution of microstructures and defects, and quantitatively analyze their effects on …

A series of halogen-substituted benzanilides have been synthesized and characterized, and
crystallization studies directed toward generation of polymorphs have been performed to …

Hydrogen bonds with organic fluorine are discussed on the background of an ongoing
controversy, with an overview on the different methods of investigation, and with many …

In this report, we investigate the binding properties of the Lewis acid tris (pentafluorophenyl)
borane with a Lewis base semiconducting polymer, PFPT, and the subsequent mechanism …