Nanoparticle self-assembly: from interactions in suspension to polymer nanocomposites

AC Genix, J Oberdisse - Soft Matter, 2018 - pubs.rsc.org
Recent experimental results using in particular small-angle scattering to characterize the self-
assembly of mainly hard spherical nanoparticles into higher ordered structures ranging from …

Spatiotemporal Studies of Soluble Inorganic Nanostructures with X‐rays and Neutrons

JF Yin, L Amidani, J Chen, M Li, B Xue… - Angewandte Chemie …, 2024 - Wiley Online Library
This Review addresses the use of X‐ray and neutron scattering as well as X‐ray absorption
to describe how inorganic nanostructured materials assemble, evolve, and function in …

How tuning interfaces impacts the dynamics and structure of polymer nanocomposites simultaneously

AC Genix, V Bocharova, B Carroll… - … Applied Materials & …, 2023 - ACS Publications
Fundamental understanding of the macroscopic properties of polymer nanocomposites
(PNCs) remains difficult due to the complex interplay of microscopic dynamics and structure …

ZnO nanoparticle/poly (vinyl alcohol) nanocomposites via microwave-assisted sol–gel synthesis for structural materials, UV shielding, and antimicrobial activity

IM Factori, JM Amaral, PH Camani… - ACS Applied Nano …, 2021 - ACS Publications
Polymer nanocomposites based on poly (vinyl alcohol)(PVA) and ZnO hold a privileged
position in the development of organic/inorganic hybrid multifunctional materials for …

Comprehensive characterization of APTES surface modifications of hydrous boehmite nanoparticles

A Zarinwall, T Waniek, R Saadat, U Braun, H Sturm… - Langmuir, 2020 - ACS Publications
Hydrous boehmite (γ-AlOOH) nanoparticles (BNP) show great potential as nanoscale filler
for the fabrication of fiber reinforced nanocomposite materials. Notably, the particle–matrix …

Effects of Curing Temperature and Silica Content on the Structure and Properties of a Sol–Gel PU-Silica Hybrid Coating for Corrosion Protection

ÁG Braz, DJ Pochapski, SH Pulcinelli… - ACS Applied …, 2023 - ACS Publications
Adjustments of the curing temperature and silica content were used to improve the corrosion
protection properties of an organic–inorganic hybrid (OIH) coating based on a polyurethane …

Influence of silane coupling agents on filler network structure and stress-induced particle rearrangement in elastomer nanocomposites

D Presto, J Meyerhofer, G Kippenbrock… - … Applied Materials & …, 2020 - ACS Publications
Filled rubber materials are key in many technologies having a broad impact on the economy
and sustainability, the most obvious being tire technology. Adding filler dramatically …

Structural identification of percolation of nanoparticles

D Musino, AC Genix, E Chauveau, T Bizien… - Nanoscale, 2020 - pubs.rsc.org
We propose a method relying on structural measurements by small-angle scattering to
quantitatively follow aggregation of nanoparticles (NPs) in concentrated colloidal …

Genetic algorithms and machine learning for predicting surface composition, structure, and chemistry: a historical perspective and assessment

J Roberts, JRS Bursten, C Risko - Chemistry of Materials, 2021 - ACS Publications
Genetic algorithms (GA) and machine learning (ML) have a long history of development and
use in chemistry. Recent algorithmic and computational advances, however, have brought …

The Payne effect: Primarily polymer-related or filler-related phenomenon?

N Warasitthinon, AC Genix, M Sztucki… - Rubber Chemistry …, 2019 - meridian.allenpress.com
The hysteretic softening at small dynamic strains (Payne effect)—related to the rolling
resistance and viscoelastic losses of tires—was studied as a function of particle size, filler …