{Tl[Au(C6Cl5)2]}n: A Vapochromic Complex
EJ Fernández, JM López-de-Luzuriaga… - Journal of the …, 2003 - ACS Publications
The X-ray structure of {Tl [Au (C6Cl5) 2]} n, 1, consists of 1-D linear polymer chains parallel
to the crystallographic z axis. The crystal structure of 1 has channels that run parallel to …
to the crystallographic z axis. The crystal structure of 1 has channels that run parallel to …
Recent developments in arylgold (I) chemistry
EJ Fernandez, A Laguna… - Advances in …, 2005 - books.google.com
Organogold derivatives have been known for almost a century. 1, 2 Although their chemistry
initially developed very slowly and no reviews of these derivatives were published until …
initially developed very slowly and no reviews of these derivatives were published until …
Luminescent Chains Formed from Neutral, Triangular Gold Complexes Sandwiching TlI and AgI. Structures of {Ag([Au(μ-C2,N3-bzim)]3)2}BF4·CH2Cl2, {Tl([Au(μ-C2,N3-bzim)]3)2}PF6·0.5THF (bzim = 1-Benzylimidazolate), and {Tl([Au(μ-C(OEt)NC6H …
A Burini, R Bravi, JP Fackler Jr, R Galassi… - Inorganic …, 2000 - ACS Publications
It has been found that several trinuclear complexes of AuI interact with silver and thallium
salts to intercalate Ag+ and Tl+ cations, thereby forming chains. The resulting sandwich …
salts to intercalate Ag+ and Tl+ cations, thereby forming chains. The resulting sandwich …
Luminescent Characterization of Solution Oligomerization Process Mediated Gold−Gold Interactions. DFT Calculations on [Au2Ag2R4L2]n Moieties
EJ Fernández, MC Gimeno, A Laguna… - Journal of the …, 2000 - ACS Publications
The optical properties of [Au2Ag2 (C6F5) 4 (OCMe2) 2] n (1) have been studied in the solid
state at room temperature and at 77 K and in acetone solution (5× 10-4 M). The crystal …
state at room temperature and at 77 K and in acetone solution (5× 10-4 M). The crystal …
Perfluoroarylgold complexes
EJ Fernández, A Laguna, ME Olmos - Coordination Chemistry Reviews, 2008 - Elsevier
The number of arylgold complexes has increased considerably, thanks to the use of
perfluoroaryl groups, which confer the compounds a higher thermodynamic and kinetic …
perfluoroaryl groups, which confer the compounds a higher thermodynamic and kinetic …
A Detailed Study of the Vapochromic Behavior of {Tl[Au(C6Cl5)2]}n
EJ Fernández, JM López-de-Luzuriaga… - Inorganic …, 2004 - ACS Publications
The linear-chain polymer {Tl [Au (C6Cl5) 2]} n, 1, reacts in the solid state and in solution with
different volatile organic compounds such as tetrahydrofuran, acetone, tetrahydrothiophene …
different volatile organic compounds such as tetrahydrofuran, acetone, tetrahydrothiophene …
Terpyridine isomerism as a tool for tuning red-to-NIR emissive properties in heteronuclear gold (i)–thallium (i) complexes
D Royo, S Moreno, M Rodríguez-Castillo… - Dalton …, 2024 - pubs.rsc.org
The polymeric linear chain [AuTl (C6Cl5) 2] n reacts with three terpyridine-type ligands
substituted with thiophene groups containing N-donor centres in different relative positions …
substituted with thiophene groups containing N-donor centres in different relative positions …
Synthesis, Structure, and Photophysical Studies of Luminescent Two-and Three-Dimensional Gold− Thallium Supramolecular Arrays
EJ Fernández, PG Jones, A Laguna… - Inorganic …, 2002 - ACS Publications
The reactions of tetrahydrofuran solutions of NBu4 [AuR2](R= C6F5, C6Cl5) with TlPF6 and
4, 4 '-bipyridine lead to the synthesis of the luminescent materials [Tl (bipy)] 2 [Au (C6F5) 2] 2 …
4, 4 '-bipyridine lead to the synthesis of the luminescent materials [Tl (bipy)] 2 [Au (C6F5) 2] 2 …
Metallophilicity: The dimerization of bis [(triphenylphosphine) gold (I)] chloronium cations
A Hamel, NW Mitzel, H Schmidbaur - Journal of the American …, 2001 - ACS Publications
The current literature reflects a rapidly growing interest in closed-shell interactions between
the metal centers of complexes of the heavy late transition elements. 1 The effects of 5d10 …
the metal centers of complexes of the heavy late transition elements. 1 The effects of 5d10 …
Theoretical and Photoluminescence Studies on the d10–s2 AuI–TlI Interaction in Extended Unsupported Chains
EJ Fernández, A Laguna… - … A European Journal, 2003 - Wiley Online Library
The reactions of solutions of TlPF6 and OPPh3 in tetrahydrofuran or acetone with NBu4
[AuR2](R= C6Cl5, C6F5) gave the new complexes [Au (C6Cl5) 2] 2 [Tl (OPPh3)][Tl …
[AuR2](R= C6Cl5, C6F5) gave the new complexes [Au (C6Cl5) 2] 2 [Tl (OPPh3)][Tl …