Weakly Coordinating Directing Groups for Ruthenium (II)‐Catalyzed C H Activation

S De Sarkar, W Liu, SI Kozhushkov… - … Synthesis & Catalysis, 2014 - Wiley Online Library
Synthetically useful functional groups, including ketones, amides, carbamates, carboxylic
acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in …

Mechanistic view of Ru-catalyzed C–H bond activation and functionalization: computational advances

C Shan, L Zhu, LB Qu, R Bai, Y Lan - Chemical Society Reviews, 2018 - pubs.rsc.org
Ru-Catalyzed aromatic C–H bond activation and functionalization have emerged as
important topics because they have resulted in remarkable progress in organic synthesis …

Cobalt-catalyzed C–H activation

M Moselage, J Li, L Ackermann - ACS Catalysis, 2016 - ACS Publications
Catalytic C–H activation has emerged as a powerful tool for sustainable syntheses. In the
recent years, notable success was achieved with the development of cobalt-catalyzed C–H …

Robust ruthenium (II)-catalyzed C–H arylations: carboxylate assistance for the efficient synthesis of angiotensin-II-receptor blockers

L Ackermann - Organic Process Research & Development, 2015 - ACS Publications
Ruthenium (II) complexes have emerged as effective catalysts for C–H arylations of
tetrazolyl-substituted arenes by chelation assistance. Particularly, bifunctional additives …

Oxazolinyl-assisted C–H amidation by cobalt (III) catalysis

R Mei, J Loup, L Ackermann - ACS Catalysis, 2016 - ACS Publications
Cobalt-catalyzed C–H activation by means of oxazolinyl assistance set the stage for
versatile direct amidations with ample substrate scope. Thus, a high-valent cobalt (III) …

Sequential meta-/ortho-C–H Functionalizations by One-Pot Ruthenium(II/III) Catalysis

K Korvorapun, N Kaplaneris, T Rogge, S Warratz… - ACS …, 2018 - ACS Publications
Sequential twofold meta-C–H/ortho-C–H functionalization was achieved by means of
versatile ruthenium (II) biscarboxylate catalysis. The double C–H activation proved viable in …

C H Alkenylations with Alkenyl Acetates, Phosphates, Carbonates, and Carbamates by Cobalt Catalysis at 23° C

M Moselage, N Sauermann, SC Richter… - Angewandte Chemie …, 2015 - Wiley Online Library
Inexpensive cobalt catalysts with N‐heterocyclic carbene ligands enable direct arene
alkenylations with easily accessible alkenyl acetates through regioselective C H/C O …

Rhodium catalyzed template-assisted distal para-C–H olefination

U Dutta, S Maiti, S Pimparkar, S Maiti, LR Gahan… - Chemical …, 2019 - pubs.rsc.org
Rhodium catalysis has been extensively used for ortho-C–H functionalization reactions, and
successfully extended to meta-C–H functionalization. Its application to para-C–H activation …

Recent advances in C–H bond functionalization with ruthenium-based catalysts

KS Singh - Catalysts, 2019 - mdpi.com
The past decades have witnessed rapid development in organic synthesis via catalysis,
particularly the reactions through C–H bond functionalization. Transition metals such as Pd …

Iridium-catalyzed branch-selective hydroarylation of vinyl ethers via C–H bond activation

Y Ebe, T Nishimura - Journal of the American Chemical Society, 2015 - ACS Publications
Iridium-Catalyzed Branch-Selective Hydroarylation of Vinyl Ethers via C–H Bond Activation |
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