Abstract α‐Diimine ligands have significantly shaped the coordination chemistry of most
transition metal complexes. Among them, bis (imino) acenaphthene ligands (BIANs) have …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Utilization of main-group metals as alternatives to transition metals in homogeneous
catalysis has become a hot research area in recent years. However, their application in …

For the last few decades, coordination chemists have seen many ligands whose role
pervades far beyond being a supporting ancillary. The ambiguity in their electronic structure …

An efficient additive-free manganese-catalyzed hydrogenation of alkenes to alkanes with
molecular hydrogen is described. This reaction is atom economic, implementing an …

Herein we disclose an iron‐catalyzed cross‐coupling reaction of propargyl ethers with
Grignard reagents. The reaction was demonstrated to be stereospecific and allows for a …

The reduction of epoxides is a powerful tool to access anti-Markovnikov alcohols, but
reported methods are poorly compatible with strongly electronically deactivated substrates …

Unsymmetric 1, 1-diboryl alkenes bearing one−[BPin](BPin= pinacolatoboryl) and
one−[BDan](BDan= 1, 8-diaminonaphthalatoboryl) substituent each were hydrogenated in …

In this work, a Keggin-type platinum substituted polyoxometalate (POM) is constructed by the
reaction of monolacunary phosphotungstate precursor [PW11O39] 7–with chloroplatinic …

Cobalt complexes with multiproton-and multielectron-responsive ligands are of interest for
challenging catalytic transformations. The chemical and redox noninnocence of pentane-2 …