Carbon monoxide (CO) is an endogenously produced gaseous signaling molecule with
demonstrated pharmacological effects. In studying CO biology, three delivery forms have …

An efficient additive‐free manganese‐catalyzed hydrogenation of nitriles to primary amines
with molecular hydrogen is described. The pre‐catalyst, a well‐defined bench‐stable alkyl …

A class of organomanganese hydrogenation catalysts was recently rediscovered. These are
simple dinuclear Mn (I) carbonyl compounds with phosphido (PR2−) and hydrido (H−) …

Mn complexes with amino acid derived PN ligands were used in the catalytic transfer
hydrogenation (TH) of ketone and chalcone substrates in 2-propanol with mild heating …

Context A large number of manganese and rhenium tricarbonyl complexes are known in
literature along with various applications in different fields. CO-releasing molecules …

Reactions facilitating inversion of alkene stereochemistry are rare, sought-after
transformations in the field of modern organic synthesis. Although a number of isomerization …

Dinuclear manganese hydride complexes of the form [Mn2 (CO) 8 (μ‐H)(μ‐PR2)](R= Ph, 1;
R= iPr, 2) were used in E‐selective alkyne semi‐hydrogenation (E‐SASH) catalysis. Catalyst …

Manganese complexes have been considered as a cheap and readily available alternative
to commonly used precious metal catalysts in C–C bond coupling reactions. Although high …

Manganese ([Mn (CO) 3]) and rhenium tricarbonyl ([Re (CO) 3]) complexes represent a
workhorse family of compounds with applications in a variety of fields. Here, the …

For the first time the crystal structure of a permethylated metallocene anion has been
obtained. The 17 valence electron complex decamethylmanganocene Cp* 2Mn is reduced …