The electronic properties and relatively small size of fluorine endow it with considerable
versatility as a bioisostere and it has found application as a substitute for lone pairs of …

The organic chemistry of the pentafluorosulfanyl (SF5) group, previously reviewed 1 and
extensively developed by Gard, has only recently come under more widespread …

New liquid crystals with very low viscosity, good mesophase behavior, and high reliability
are necessary to achieve the breakthrough from flat computer monitors to large displays for …

Abstract (Hetero) arylsulfur compounds where the S atom is in the oxidation state VI
represent a large percentage of the molecular functionalities present in organic chemistry …

The pentafluorosulphanyl group (SF5) is a highly stable chemical function which has been
attracting a great deal of interest owing to its peculiar chemical, structural, physicochemical …

Abstract Pentafluorosulfanyl (SF5)‐containing compounds and corresponding analogs are a
highly valuable class of fluorine‐containing building blocks owing to their unique properties …

The success of fluorinated molecules in drug design has led medicinal chemists to search
for new fluorine‐containing substituents. A major recently developed group is the …

Various arylsulfur pentafluorides, ArSF 5, have long been desired in both academic and
industrial areas, and ArSF 5 compounds have attracted considerable interest in many areas …

Modern pentafluorosulfanyl (SF5) chemistry has an Achilles heel: synthetic accessibility.
Herein, we present the first approach to aryl‐SF4Cl compounds (key intermediates in state …

1-Pentafluorosulfanyl acetylene and its derivatives react with azide or diazomethane giving
rise to an SF5-substituted 1, 2, 3-triazole or pyrazole. The SF5 group increases density …