Magnetism is a phenomenon that has always captured the imagination of humans. Its
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …

Polynuclear μ-oxo complexes are commonly observed for second and third row transition
metals. This review is particularly interested in the μ 3-oxo-bridged ruthenium trinuclear …

Metal–organic frameworks (MOFs) are crystalline nanoporous materials comprised of
organic electron donors linked to metal ions by strong coordination bonds. Applications such …

Mixed-valence compounds were recognized by chemists more than a century ago for their
unusual colours and stoichiometries, but it was just 40 years ago that two seminal articles …

The formation of high-valent states is a key factor in making highly active transition-metal-
based catalysts of the oxygen evolution reaction (OER). These high oxidation states will be …

This article describes research from our laboratory on the chemistry and spectroscopic
properties of inorganic mixed-valence complexes. After a brief review of the seminal work of …

The purpose of this review is to examine the fundamental differences between
intermolecular self-exchange vs. intramolecular ET in mixed-valence complexes based on …

The Robin–Day class II/III mixed-valence character is established quantum-chemically for a
series of mixed-valence diquinone radical anions. Particular emphasis is placed on the …

The diverse structures and rich electrochemical response of polynuclear complexes have
made them attractive objects with which to study bridge-mediated electronic interactions. In …

Application of a semiclassical three-state model of mixed valency to complexes of the type
[Ru3 (μ3-O)(OAc) 6 (CO)(py)–(μ2-BL)–Ru3 (μ3-O)(OAc) 6 (CO)(py)]− 1, where BL= 1, 4 …