Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction

M Lu, M Zhang, J Liu, TY Yu, JN Chang… - Journal of the …, 2022 - ACS Publications
Single clusters have attracted extensive research interest in the field of catalysis. However,
achieving a highly uniform dispersion of a single-cluster catalyst is challenging. In this work …

Linker Engineering for Reactive Oxygen Species Generation Efficiency in Ultra-Stable Nickel-Based Metal–Organic Frameworks

K Wu, XY Liu, PW Cheng, YL Huang… - Journal of the …, 2023 - ACS Publications
Interfacial charge transfer on the surface of heterogeneous photocatalysts dictates the
efficiency of reactive oxygen species (ROS) generation and therefore the efficiency of …

Trace to the source: self‐tuning of MOF photocatalysts

Z Qian, R Zhang, Y Xiao, H Huang… - Advanced Energy …, 2023 - Wiley Online Library
Benefitting from ultra‐high porosity, large specific surface area (SSA), and rich active sites,
metal–organic frameworks (MOFs) have emerged as a star material in energy and …

Metal–organic frameworks as a platform for clean energy applications

X Li, X Yang, H Xue, H Pang, Q Xu - EnergyChem, 2020 - Elsevier
Abstract Metal–organic frameworks (MOFs), an emerging class of porous materials, have
shown intriguing and promising properties in a wide range of applications due to their …

Polyoxometalate@ metal–organic framework composites as effective photocatalysts

Y Liu, C Tang, M Cheng, M Chen, S Chen, L Lei… - ACS …, 2021 - ACS Publications
In the recent years, polyoxometalate (POM) encapsulated metal–organic framework (MOF)
composites have attracted much attention in photocatalysis. Both POMs and MOFs have …

Merging molecular catalysts and metal–organic frameworks for photocatalytic fuel production

PM Stanley, J Haimerl, NB Shustova, RA Fischer… - Nature Chemistry, 2022 - nature.com
In the effort to generate sustainable clean energy from abundant resources such as water
and carbon dioxide, solar fuel production—the combination of solar-light harvesting and the …

Polypyridyl Ru (II) or cyclometalated Ir (III) functionalized architectures for photocatalysis

YL Li, AJ Li, SL Huang, JJ Vittal, GY Yang - Chemical Society Reviews, 2023 - pubs.rsc.org
The chemistry of polypyridyl Ru (II) and cyclometalated Ir (III) derivatives provides long-
lasting interest to researchers due to the inherent advantage of their triplet states in a variety …

Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis

P Mialane, C Mellot-Draznieks, P Gairola… - Chemical Society …, 2021 - pubs.rsc.org
The last few years have seen huge growing interest in the heterogenisation of molecular
catalysts since it allows combining the advantages of homogeneous and heterogeneous …