Biocatalytic cascades are a powerful tool for building complex molecules containing oxygen
and nitrogen functionalities. Moreover, the combination of multiple enzymes in one pot offers …

Mid-to-long-chain dicarboxylic acids (DCA i, i≥ 6) are organic compounds in which two
carboxylic acid functional groups are present at the terminal position of the carbon chain …

Aliphatic α, ω‐diamines (DAs) are important monomer precursors that are industrially
produced by energy‐intensive, multistage chemical reactions that are harmful to the …

Global proteome changes in microbes affect the survival and overall production of
commercially relevant metabolites through different bioprocesses. The existing methods to …

Aliphatic ω‐amino fatty acids (ω‐AFAs) and α, ω‐diamines (α, ω‐DMs) are essential
monomers for the production of nylons. Development of a sustainable biosynthesis route for …

Highlights•Bioproduced hydroxy acids (HAs) and diols are sustainable plastics
precursors.•Novel pathway design allows for the bioproduction of new-to-nature HAs and …

Oxyfunctionalization of renewable oleic acid is an environmentally friendly process for
producing C9 bifunctional chemicals, ie, 9-hydroxynonanoic acid and its derivatives …

The selective oxyfunctionalization of unsaturated fatty acids is difficult in chemical reactions,
whereas regio-and stereoselective oxyfunctionalization is often performed in biocatalytic …

Engineering of native and recombinant enzyme reactions in whole-cell biocatalysis may
allow the production of a variety of chemicals. In particular, fine-tuning of the reaction …

A multienzymatic cascade for the synthesis of 1, 6-hexamethylenediamine (HMD) and
related α, ω-diamines from corresponding cycloalkanols is reported herein. In this work, an E …