The role of gold in transition metal carbonyl clusters
I Ciabatti, C Femoni, MC Iapalucci, S Ruggieri… - Coordination Chemistry …, 2018 - Elsevier
In this review, the authors describe the role of gold in the chemistry of transition metal
carbonyl clusters, a field that has been very active over the past fifty years. Both homo-and …
carbonyl clusters, a field that has been very active over the past fifty years. Both homo-and …
Substituted Metal Carbonyls. 27.1 Synthesis, Structures, and Metal− Metal Bonding of a Ferrocenylphosphine exo-Bridged Cluster with Two Heterometallic Triangles …
PMN Low, AL Tan, TSA Hor, YS Wen, LK Liu - Organometallics, 1996 - ACS Publications
Redox condensation of PPN [Mn2 (CO) 8 (μ-PPh2)](1;(PPN= N (PPh3) 2) with Au2Cl2 (μ-P−
P)(P− P=(C5H4PPh2) 2Fe (dppf), Ph2PC2H4PPh2 (dppe)) gives two hexanuclear Au− Mn …
P)(P− P=(C5H4PPh2) 2Fe (dppf), Ph2PC2H4PPh2 (dppe)) gives two hexanuclear Au− Mn …
Electrophilic Additions of AuPR3+ and Au2 (. mu.-L) 2+(L= Diphosphine) Units to the [Fe3 (CO) 11] 2-Anion
O Rossell, M Seco, R Reina, M Font-Bardia… - …, 1994 - ACS Publications
The reaction of (PPh4) 2 [Fe3 (CO)¡ J with (AuCl) 2Íg-L)(L= dppm, dppe) orAuCIPRs {R= Ph,
Me) in tetrahydrofuran invariably gives mixed iron/gold clusters in whichthe gold atoms …
Me) in tetrahydrofuran invariably gives mixed iron/gold clusters in whichthe gold atoms …
α–βAlkenyl isomerisation at diiron centres
MK Anwar, G Hogarth, OS Senturk, W Clegg… - Journal of the …, 2001 - pubs.rsc.org
α-Substituted alkenyl complexes [Fe2 (CO) 6 (μ-RCCH2)(μ-PPh2)] 1a–1e (R= Ph, Me, Prn,
Bun or But) have been prepared via regioselective hydrodimetallation of primary alkynes by …
Bun or But) have been prepared via regioselective hydrodimetallation of primary alkynes by …
Anionic iron clusters as building blocks for the synthesis of higher nuclearity compounds containing 11-and 12-group elements
M Ferrer, R Reina, O Rossell, M Seco - Coordination Chemistry Reviews, 1999 - Elsevier
Anionic iron clusters have been widely used as building blocks for the formation of mixed
metal clusters with 11-and 12-group elements. This review summarizes the results reported …
metal clusters with 11-and 12-group elements. This review summarizes the results reported …
Towards linked clusters: reactions of [Ru6 (CO) 17B]− with dppm and [ClAu (L–L) AuCl](L–L= bis (diphenylphosphino)-alkanes,-ethene and-ethyne, and the crystal …
CE Housecroft, AL Rheingold, A Waller… - Journal of organometallic …, 1998 - Elsevier
The reaction between [(PPh3) 2N][Ru6 (CO) 17B] and bis (diphenylphosphino) methane
(dppm) followed by protonation gives [HRu6 (CO) 15 (P, P′-dppm)] in high yield; its …
(dppm) followed by protonation gives [HRu6 (CO) 15 (P, P′-dppm)] in high yield; its …
Substituted metal carbonyls: XXII. Synthesis of 1, 1′-bis (diphenylphosphino) ferrocene-bridged complexes with two heterometallic Au M (M Mn and Re) bonds
PMN Low, YK Yan, HSO Chan, TSA Hor - Journal of organometallic …, 1993 - Elsevier
Abstract AU 2 Cl 2 (μ-1, 1′-bis (diphenylphosphino) ferrocene (dppf) reacts with Na [M (CO)
5] to give [AuM (CO) 5] 2 (μ-dppf)(M Re (1); M Mn (2)) in 45% and 71% yields …
5] to give [AuM (CO) 5] 2 (μ-dppf)(M Re (1); M Mn (2)) in 45% and 71% yields …
Unprecedented trimetallic cluster with an in-plane. mu. 3-hydride ligand. X-ray crystal structure of [Mo2 (CO) 8 (. mu.-dppm)(. mu. 3-H)(. mu.-AuPPh3)]
Introduction The synthesis, structural characterization, and reactivity study of gold hydride
species is a rapidly expanding area because of their potential use in the field of …
species is a rapidly expanding area because of their potential use in the field of …
Synthesis and Electrochemical and EPR Studies of Spiked Butterfly Metal Clusters Containing an Fe3HgM Core (M= Mo, W, Fe, Mn, Co)
R Reina, O Rossell, M Seco, R Zquiak… - …, 1994 - ACS Publications
The use of anionic carbonyl clusters for condensation reactions with gold (I) or mercury (II)
salts has been shown to be a powerful method for the formation of mixed-metal clusters. 1, 2 …
salts has been shown to be a powerful method for the formation of mixed-metal clusters. 1, 2 …
The versatile nature of [ClAu (L–L) AuCl](L–L= bis (diphenylphosphino) methane (dppm) or-butane (dppb)) in reactions with [Rh2Ru4 (CO) 16B]−: crystal structures of …
AD Hattersley, CE Housecroft, AL Rheingold - Inorganica chimica acta, 1999 - Elsevier
The reaction of the octahedral borido cluster [Rh2Ru4 (CO) 16B]−(which exists as trans and
cis isomers with respect to the Rh sites) with [ClAu (dppb) AuCl](dppb= bis …
cis isomers with respect to the Rh sites) with [ClAu (dppb) AuCl](dppb= bis …