Gyroscopes and the chemical literature, 2002–2020: approaches to a nascent family of molecular devices

A Ehnbom, JA Gladysz - Chemical Reviews, 2021 - ACS Publications
Research directed toward the goal of molecular gyroscopes since the coverage of a
previous review (2002) is described. Such species are a subclass of molecular rotors, which …

Ultrathin two-dimensional porous organic nanosheets with molecular rotors for chemical sensing

J Dong, K Zhang, X Li, Y Qian, H Zhu, D Yuan… - Nature …, 2017 - nature.com
Molecular rotors have played an important role in recent materials chemistry. Although
several studies on functional materials containing molecular rotors have been reported for …

Order–disorder transition of dipolar rotor in a crystalline molecular gyrotop and its optical change

W Setaka, K Yamaguchi - Journal of the American Chemical …, 2013 - ACS Publications
Successful control of the orientation of the π-electron systems in media has been achieved
in certain liquid crystals, making them applicable to devices for optical systems because of …

Pd-catalyzed steroid reactions

D Czajkowska-Szczykowska, JW Morzycki… - Steroids, 2015 - Elsevier
We review the most important achievements of the last decade in the field of steroid
synthesis in the presence of palladium catalysts. Various palladium-catalyzed cross …

Gyroscope-Like Complexes Based on Dibridgehead Diphosphine Cages That Are Accessed by Three-Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)3, Fe(CO)2(NO)+ …

GM Lang, T Shima, L Wang, KJ Cluff… - Journal of the …, 2016 - ACS Publications
Reactions of trans-Fe (CO) 3 (P ((CH2) m CH CH2) 3) 2 (m= a/4; b/5, c/6, e/8) and Grubbs'
catalyst (12–24 mol%, CH2Cl2, reflux) give the cage-like trienes trans-Fe (CO) 3 (P ((CH2) …

Amphidynamic crystals of a steroidal bicyclo [2.2. 2] octane rotor: a high symmetry group that rotates faster than smaller methyl and methoxy groups

B Rodríguez-Molina, S Pérez-Estrada… - Journal of the …, 2013 - ACS Publications
The synthesis, crystallization, single crystal X-ray structure, and solid state dynamics of
molecular rotor 3 provided with a high symmetry order and relatively cylindrical bicyclo [2.2 …

Exploiting rotational motion in molecular crystals

L Catalano, P Naumov - CrystEngComm, 2018 - pubs.rsc.org
Various aspects of molecular motion in crystals have been extensively studied in different
research fields of chemistry as a valuable source of structural and dynamic information en …

Thermodynamic evaluation of aromatic CH/π interactions and rotational entropy in a molecular rotor

S Perez-Estrada, B Rodrı́guez-Molina… - Journal of the …, 2015 - ACS Publications
A molecular rotor built with a stator formed by two rigid 9β-mestranol units having a 90° bent
angle linked to a central phenylene rotator has an ideal structure to examine aromatic CH/π …

Synthesis of crystalline molecular gyrotops and phenylene rotation inside the cage

W Setaka, K Inoue, S Higa, S Yoshigai… - The Journal of …, 2014 - ACS Publications
Phenylene-bridged macrocage molecules were synthesized as molecular gyrotops because
the rotor can rotate even in a crystal. The chain-length-dependent properties of the …

Montmorillonite Catalyzed Synthesis of Novel Steroid Dimers

AM Tomkiel, AD Majewski, L Siergiejczyk, JW Morzycki - Molecules, 2023 - mdpi.com
The reactions of sterols (androst-5-en-3β-ol-17-one, diosgenin, and cholesterol) and their
tosylates with hydroquinone aimed at the synthesis of O, O-1, 4-phenylene-linked steroid …