Gyroscopes and the chemical literature, 2002–2020: approaches to a nascent family of molecular devices
A Ehnbom, JA Gladysz - Chemical Reviews, 2021 - ACS Publications
Research directed toward the goal of molecular gyroscopes since the coverage of a
previous review (2002) is described. Such species are a subclass of molecular rotors, which …
previous review (2002) is described. Such species are a subclass of molecular rotors, which …
Ultrathin two-dimensional porous organic nanosheets with molecular rotors for chemical sensing
Molecular rotors have played an important role in recent materials chemistry. Although
several studies on functional materials containing molecular rotors have been reported for …
several studies on functional materials containing molecular rotors have been reported for …
Order–disorder transition of dipolar rotor in a crystalline molecular gyrotop and its optical change
W Setaka, K Yamaguchi - Journal of the American Chemical …, 2013 - ACS Publications
Successful control of the orientation of the π-electron systems in media has been achieved
in certain liquid crystals, making them applicable to devices for optical systems because of …
in certain liquid crystals, making them applicable to devices for optical systems because of …
Pd-catalyzed steroid reactions
D Czajkowska-Szczykowska, JW Morzycki… - Steroids, 2015 - Elsevier
We review the most important achievements of the last decade in the field of steroid
synthesis in the presence of palladium catalysts. Various palladium-catalyzed cross …
synthesis in the presence of palladium catalysts. Various palladium-catalyzed cross …
Gyroscope-Like Complexes Based on Dibridgehead Diphosphine Cages That Are Accessed by Three-Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)3, Fe(CO)2(NO)+ …
GM Lang, T Shima, L Wang, KJ Cluff… - Journal of the …, 2016 - ACS Publications
Reactions of trans-Fe (CO) 3 (P ((CH2) m CH CH2) 3) 2 (m= a/4; b/5, c/6, e/8) and Grubbs'
catalyst (12–24 mol%, CH2Cl2, reflux) give the cage-like trienes trans-Fe (CO) 3 (P ((CH2) …
catalyst (12–24 mol%, CH2Cl2, reflux) give the cage-like trienes trans-Fe (CO) 3 (P ((CH2) …
Amphidynamic crystals of a steroidal bicyclo [2.2. 2] octane rotor: a high symmetry group that rotates faster than smaller methyl and methoxy groups
B Rodríguez-Molina, S Pérez-Estrada… - Journal of the …, 2013 - ACS Publications
The synthesis, crystallization, single crystal X-ray structure, and solid state dynamics of
molecular rotor 3 provided with a high symmetry order and relatively cylindrical bicyclo [2.2 …
molecular rotor 3 provided with a high symmetry order and relatively cylindrical bicyclo [2.2 …
Exploiting rotational motion in molecular crystals
L Catalano, P Naumov - CrystEngComm, 2018 - pubs.rsc.org
Various aspects of molecular motion in crystals have been extensively studied in different
research fields of chemistry as a valuable source of structural and dynamic information en …
research fields of chemistry as a valuable source of structural and dynamic information en …
Thermodynamic evaluation of aromatic CH/π interactions and rotational entropy in a molecular rotor
S Perez-Estrada, B Rodrı́guez-Molina… - Journal of the …, 2015 - ACS Publications
A molecular rotor built with a stator formed by two rigid 9β-mestranol units having a 90° bent
angle linked to a central phenylene rotator has an ideal structure to examine aromatic CH/π …
angle linked to a central phenylene rotator has an ideal structure to examine aromatic CH/π …
Synthesis of crystalline molecular gyrotops and phenylene rotation inside the cage
W Setaka, K Inoue, S Higa, S Yoshigai… - The Journal of …, 2014 - ACS Publications
Phenylene-bridged macrocage molecules were synthesized as molecular gyrotops because
the rotor can rotate even in a crystal. The chain-length-dependent properties of the …
the rotor can rotate even in a crystal. The chain-length-dependent properties of the …
Montmorillonite Catalyzed Synthesis of Novel Steroid Dimers
AM Tomkiel, AD Majewski, L Siergiejczyk, JW Morzycki - Molecules, 2023 - mdpi.com
The reactions of sterols (androst-5-en-3β-ol-17-one, diosgenin, and cholesterol) and their
tosylates with hydroquinone aimed at the synthesis of O, O-1, 4-phenylene-linked steroid …
tosylates with hydroquinone aimed at the synthesis of O, O-1, 4-phenylene-linked steroid …