[HTML][HTML] Frontiers of on-surface synthesis: From principles to applications

Q Shen, HY Gao, H Fuchs - Nano Today, 2017 - Elsevier
On-surface synthesis is the bottom-up construction of covalent bonds between molecular
building blocks, which has been greatly developed during the past decade. Dozens of …

Atomic force microscopy for molecular structure elucidation

L Gross, B Schuler, N Pavliček… - Angewandte Chemie …, 2018 - Wiley Online Library
Using scanning probe microscopy techniques, at low temperatures and in ultrahigh vacuum,
individual molecules adsorbed on surfaces can be probed with ultrahigh resolution to …

Unraveling the molecular structures of asphaltenes by atomic force microscopy

B Schuler, G Meyer, D Peña, OC Mullins… - Journal of the American …, 2015 - ACS Publications
Petroleum is one of the most precious and complex molecular mixtures existing. Because of
its chemical complexity, the solid component of crude oil, the asphaltenes, poses an …

Overview of asphaltene nanostructures and thermodynamic applications

B Schuler, Y Zhang, F Liu, AE Pomerantz… - Energy & …, 2020 - ACS Publications
Previously, asphaltene science had been hindered by many significant uncertainties
regarding molecular weight, molecular structure, and nanocolloidal characteristics in …

Multiple heteroatom substitution to graphene nanoribbon

S Kawai, S Nakatsuka, T Hatakeyama, R Pawlak… - Science …, 2018 - science.org
Substituting heteroatoms into nanostructured graphene elements, such as graphene
nanoribbons, offers the possibility for atomic engineering of electronic properties. To …

Reversible Bergman cyclization by atomic manipulation

B Schuler, S Fatayer, F Mohn, N Moll, N Pavliček… - Nature …, 2016 - nature.com
The Bergman cyclization is one of the most fascinating rearrangements in chemistry, with
important implications in organic synthesis and pharmacology. Here we demonstrate a …

On-surface generation and imaging of arynes by atomic force microscopy

N Pavliček, B Schuler, S Collazos, N Moll, D Pérez… - Nature …, 2015 - nature.com
Reactive intermediates are involved in many chemical transformations. However, their
characterization is a great challenge because of their short lifetimes and high reactivities …

Imaging the halogen bond in self-assembled halogenbenzenes on silver

Z Han, G Czap, C Chiang, C Xu, PJ Wagner, X Wei… - Science, 2017 - science.org
Halogens are among the most electronegative elements, and the variations in size and
polarizability of halogens require different descriptions of the intermolecular bonds they …

High resolution SPM imaging of organic molecules with functionalized tips

P Jelínek - Journal of Physics: Condensed Matter, 2017 - iopscience.iop.org
One of the most remarkable and exciting achievements in the field of scanning probe
microscopy (SPM) in the last years is the unprecedented sub-molecular resolution of both …

Imaging single-molecule reaction intermediates stabilized by surface dissipation and entropy

A Riss, AP Paz, S Wickenburg, HZ Tsai… - Nature …, 2016 - nature.com
Chemical transformations at the interface between solid/liquid or solid/gaseous phases of
matter lie at the heart of key industrial-scale manufacturing processes. A comprehensive …