Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Single-atom catalysts based on the metal–oxide interaction

R Lang, X Du, Y Huang, X Jiang, Q Zhang… - Chemical …, 2020 - ACS Publications
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …

Chemical synthesis of single atomic site catalysts

S Ji, Y Chen, X Wang, Z Zhang, D Wang, Y Li - Chemical reviews, 2020 - ACS Publications
Manipulating metal atoms in a controllable way for the synthesis of materials with the
desired structure and properties is the holy grail of chemical synthesis. The recent …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Fine-tuned local coordination environment of Pt single atoms on ceria controls catalytic reactivity

W Tan, S Xie, D Le, W Diao, M Wang, KB Low… - Nature …, 2022 - nature.com
Constructing single atom catalysts with fine-tuned coordination environments can be a
promising strategy to achieve satisfactory catalytic performance. Herein, via a simple …

The effect of coordination environment on the activity and selectivity of single-atom catalysts

Y Zhang, J Yang, R Ge, J Zhang, JM Cairney… - Coordination Chemistry …, 2022 - Elsevier
Traditional heterogeneous catalysts with noble metals as active sites only have surface-
active substances involved in the catalytic reactions, which greatly reduces the material …

Advanced support materials and interactions for atomically dispersed noble‐metal catalysts: from support effects to design strategies

X Sui, L Zhang, J Li, K Doyle‐Davis, R Li… - Advanced Energy …, 2022 - Wiley Online Library
Indisputably, noble‐metal single atom catalysts (SACs) are one of the most popular research
topics in the field of catalysis because of their low cost, ultrahigh atomic utilization, and …

[HTML][HTML] Towards dense single-atom catalysts for future automotive applications

A Beniya, S Higashi - Nature Catalysis, 2019 - nature.com
CO oxidation is an important primary reaction in automotive catalysis, and has been studied
extensively since the 1970s because of its fundamental nature and technological relevance …

[HTML][HTML] Single-atom catalysts: advances and challenges in metal-support interactions for enhanced electrocatalysis

Y Mu, T Wang, J Zhang, C Meng, Y Zhang… - Electrochemical Energy …, 2022 - Springer
Abstract Single-atom catalysts (SACs), which contain a single metal atom supported on a
well-confined substrate, are among the most promising heterogeneous catalysts owing to …