Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Suppression of kernel vibrations by layer-by-layer ligand engineering boosts photoluminescence efficiency of gold nanoclusters

Y Zhong, J Zhang, T Li, W Xu, Q Yao, M Lu… - Nature …, 2023 - nature.com
The restriction of structural vibration has assumed great importance in attaining bright
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …

Toward total synthesis of thiolate-protected metal nanoclusters

Q Yao, T Chen, X Yuan, J Xie - Accounts of chemical research, 2018 - ACS Publications
Conspectus Total synthesis, where desired organic-and/or biomolecules could be produced
from simple precursors at atomic precision and with known step-by-step reactions, has …

Converting nanotoxicity data to information using artificial intelligence and simulation

X Yan, T Yue, DA Winkler, Y Yin, H Zhu… - Chemical …, 2023 - ACS Publications
Decades of nanotoxicology research have generated extensive and diverse data sets.
However, data is not equal to information. The question is how to extract critical information …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Engineering functional metal materials at the atomic level

Q Yao, X Yuan, T Chen, DT Leong, J Xie - Advanced Materials, 2018 - Wiley Online Library
With continuous research efforts devoted into synthesis and characterization chemistry of
functional nanomaterials in the past decades, the development of metal materials is …