Ligand Effects on the Spin Relaxation Dynamics and Coherent Manipulation of Organometallic La(II) Potential Qudits

LE Nodaraki, AM Ariciu, DN Huh, J Liu… - Journal of the …, 2024 - ACS Publications
We present pulsed electron paramagnetic resonance (EPR) studies on three La (II)
complexes,[K (2.2. 2-cryptand)][La (Cp′) 3](1),[K (2.2. 2-cryptand)][La (Cp ″) 3](2), and [K …

VdW Mediated Strong Magnetic Exchange Interactions in Chains of Hydrogen-Free Sublimable Molecular Qubits

F Santanni, M Briganti, G Serrano, E Salvadori… - JACS Au, 2023 - ACS Publications
Sulfur-rich molecular complexes of dithiolene-like ligands are appealing candidates as
molecular spin qubits because spin coherence properties are enhanced in hydrogen-free …

Structural isomerism-tuned magnetisation relaxation dynamics in lanthanide coordination complexes

SH Hansen, CD Buch, S Piligkos - Inorganic Chemistry Frontiers, 2024 - pubs.rsc.org
The eigenspectrum and eigenvectors of the 2F7/2 ground multiplets of two structural isomer
coordination complexes, Yb (trenovan)(H3trenovan= tris (((3-methoxysalicylidene) amino) …

Exploring tunneling ESEEM beyond methyl groups in nitroxides at low temperatures

A Eggeling, T Ngendahimana, G Jeschke… - Physical Chemistry …, 2024 - pubs.rsc.org
Tunneling of methyl rotors coupled to an electron spin causes magnetic field independent
electron spin echo envelope modulation (ESEEM) at low temperatures. For nitroxides …

Systems-chart approach to the design of spin relaxation times in molecular qubits

K Mullin, D Johnson, D Freedman, J Rondinelli - Dalton Transactions, 2024 - pubs.rsc.org
Molecular qubits are a promising platform for future quantum information science
technologies; however, to find success in novel devices requires that the molecules exhibit …

Impact of ligand chlorination and counterion tuning on high-field spin relaxation in a series of V (iv) complexes

R Martinez, CE Jackson, Ö Üngör, J van Tol… - Dalton …, 2023 - pubs.rsc.org
Methods of controlling spin coherence by molecular design are essential to efforts to
develop molecular qubits for quantum information and sensing applications. In this …

Heterometallic Titanium and Potassium Complexes with Catecholate and Tetrabromocatecholate

EA Filippova, TS Sukhikh, MN Sokolov… - Journal of Structural …, 2024 - Springer
Heterometallic Titanium and Potassium Complexes with Catecholate and Tetrabromocatecholate
| Journal of Structural Chemistry Skip to main content SpringerLink Account Menu Find a …

ГЕТЕРОМЕТАЛЛИЧЕСКИЕ КОМПЛЕКСЫ ТИТАНА И КАЛИЯ С КАТЕХОЛАТОМ И ТЕТРАБРОМОКАТЕХОЛАТОМ

ЕА ФИЛИППОВА, ТС СУХИХ, МН СОКОЛОВ… - ЖУРНАЛ …, 2024 - elibrary.ru
Синтезированы комплексы титана с катехолатом (cat) и тетрабромокатехолатом
(tbc)[K 2 Ti (cat) 3 (thf) 2](1),[K 2 Ti (tbc) 3 (dme) 3](2) и [K 4 Ti (tbc) 3 (thf) 6 (m 4-O)] 2 (3) …