Dynamic nuclear polarization for sensitivity enhancement in biomolecular solid-state NMR

T Biedenbänder, V Aladin, S Saeidpour… - Chemical …, 2022 - ACS Publications
Solid-state NMR with magic-angle spinning (MAS) is an important method in structural
biology. While NMR can provide invaluable information about local geometry on an atomic …

[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR

ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …

Polarizing agents for efficient high field DNP solid-state NMR spectroscopy under magic-angle spinning: from design principles to formulation strategies

G Menzildjian, J Schlagnitweit, G Casano, O Ouari… - Chemical …, 2023 - pubs.rsc.org
Dynamic Nuclear Polarization (DNP) has recently emerged as a cornerstone approach to
enhance the sensitivity of solid-state NMR spectroscopy under Magic Angle Spinning (MAS) …

High-field dynamic nuclear polarization

B Corzilius - Annual review of physical chemistry, 2020 - annualreviews.org
Dynamic nuclear polarization (DNP) is one of the most prominent methods of sensitivity
enhancement in nuclear magnetic resonance (NMR). Even though solid-state DNP under …

Dynamic nuclear polarization with trityl radicals

RS Palani, M Mardini, Y Quan, RG Griffin - Journal of Magnetic Resonance, 2023 - Elsevier
Despite the expanding applications of dynamic nuclear polarization (DNP) to problems in
biological and materials science, there remain unresolved questions concerning DNP …

Large-enhancement nanoscale dynamic nuclear polarization near a silicon nanowire surface

S Tabatabaei, P Priyadarsi, N Singh, P Sahafi… - Science …, 2024 - science.org
Dynamic nuclear polarization (DNP) has revolutionized the field of nuclear magnetic
resonance spectroscopy, expanding its reach and capabilities to investigate diverse …

Time-optimized pulsed dynamic nuclear polarization

KO Tan, C Yang, RT Weber, G Mathies, RG Griffin - Science advances, 2019 - science.org
Pulsed dynamic nuclear polarization (DNP) techniques can accomplish electron-nuclear
polarization transfer efficiently with an enhancement factor that is independent of the …

DNP‐enhanced solid‐state NMR spectroscopy of active pharmaceutical ingredients

L Zhao, AC Pinon, L Emsley… - Magnetic Resonance in …, 2018 - Wiley Online Library
Solid‐state NMR spectroscopy has become a valuable tool for the characterization of both
pure and formulated active pharmaceutical ingredients (APIs). However, NMR generally …

Three-spin solid effect and the spin diffusion barrier in amorphous solids

KO Tan, M Mardini, C Yang, JH Ardenkjær-Larsen… - Science …, 2019 - science.org
Dynamic nuclear polarization (DNP) has evolved as the method of choice to enhance NMR
signal intensities and to address a variety of otherwise inaccessible chemical, biological and …

Large cross-effect dynamic nuclear polarisation enhancements with kilowatt inverting chirped pulses at 94 GHz

Y Zhao, H El Mkami, RI Hunter, G Casano… - Communications …, 2023 - nature.com
Dynamic nuclear polarisation (DNP) is a process that transfers electron spin polarisation to
nuclei by applying resonant microwave radiation, and has been widely used to improve the …