Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …

The presence of nitrogen atom in a wide variety of organic compounds called for the use of
powerful C− H activation strategy in the C− N bond formation. Pentamethylcyclopentadienyl …

Photocatalysis in aqueous micellar media has recently opened wide avenues to activate
strong carbon–halide bonds. So far, however, it has mainly explored strongly reducing …

Selective C− H bond functionalization catalyzed by metal complexes have completely
revolutionized the way in which chemical synthesis is conceived nowadays. Typically, the …

Despite their synthetic utility, practical methods to prepare diversely functionalized aromatic
acyl silanes (benzoyl silanes) remain scarce. We herein report that cobalt complexes can …

Indole is a ubiquitous structural motif with important applications in many areas of chemistry.
Given this, a simple and efficient Ru (II)-catalyzed synthesis of indole via intermolecular …

An efficient synthetic method has been developed for C-3 site-selective alkenylation of
indole derivatives under ruthenium (II) catalysis with an ester as a directing group. Besides …

Direct C–H bond amination is an emerging area of research among synthetic community
owing to prevalence of N-bearing scaffolds in various fields of importance to humankind. In …

An efficient methodology to form 4-alkoxy-and 4-aryloxybenzo [d][1, 2, 3] triazines via an
intramolecular heterocyclization of 1-azido-2-[isocyano (p-tosyl) methyl] benzenes under …

Herein, we report a controlled introduction of an amide unit at the ortho-position of an
electron-deficient arylamide system without affording any cyclized products using user …