Low temperature activation of methane on metal-oxides and complex interfaces: Insights from surface science

SD Senanayake, JA Rodriguez… - Accounts of Chemical …, 2020 - ACS Publications
Conspectus The abundance of cheap, natural gas has transformed the energy landscape,
whereby revealing new possibilities for sustainable chemical technologies or impacting …

Theoretical Perspective of Promoting Direct Methane-to-Methanol Conversion at Complex Metal Oxide–Metal Interfaces

E Huang, P Liu - The Journal of Physical Chemistry Letters, 2023 - ACS Publications
Direct methane conversion to methanol has been considered as an effective and economic
way to address greenhouse effects and the current high demand for methanol in industry …

Selective Methane Oxidation to Methanol on ZnO/Cu2O/Cu(111) Catalysts: Multiple Site-Dependent Behaviors

E Huang, I Orozco, PJ Ramírez, Z Liu… - Journal of the …, 2021 - ACS Publications
Because of the abundance of natural gas in our planet, a major goal is to achieve a direct
methane-to-methanol conversion at medium to low temperatures using mixtures of methane …

C1 Chemistry on Metal Carbide Nanoparticles: Boosting the Conversion of CO2 and CH4

JA Rodriguez, C Jimenez-Orozco… - The Journal of …, 2023 - ACS Publications
The studies described in this Perspective show that transition metal carbide (TMC)
nanoparticles can be very useful for the activation of three molecules located at the heart of …

Supported Molybdenum Carbide Nanoparticles as an Excellent Catalyst for CO2 Hydrogenation

M Figueras, RA Gutierrez, F Vines, PJ Ramirez… - Acs …, 2021 - ACS Publications
Experiments under controlled conditions show that MoC x nanoclusters supported on an
inert Au (111) support are efficient catalysts for CO2 conversion, although with a prominent …

Recent advances in carbon dioxide adsorption, activation and hydrogenation to methanol using transition metal carbides

P Ranjan, VB Saptal, JK Bera - ChemSusChem, 2022 - Wiley Online Library
The inevitable emission of carbon dioxide (CO2) due to the burning of a substantial amount
of fossil fuels has led to serious energy and environmental challenges. Metal‐based …

Catalytic activity of Ti‐based MXenes for the hydrogenation of furfural

M Naguib, W Tang, KL Browning, GM Veith… - …, 2020 - Wiley Online Library
Herein we report on the catalytic activity of Ti‐based MXenes (Ti3CNTz and Ti3C2Tz) for
biomass transformation. MXenes were found to be active catalysts for the hydrogenation of …

Co-activation of methane and nitrogen to acetonitrile over MoC x/Al 2 O 3 catalysts

K Trangwachirachai, IT Kao, WH Huang… - Catalysis Science & …, 2023 - pubs.rsc.org
Methane and nitrogen are regarded as the most abundant sources of hydrocarbons and
nitrogen, respectively. Both compounds exhibit high stability due to the presence of daunting …

Surface characterization and methane activation on SnO x/Cu 2 O/Cu (111) inverse oxide/metal catalysts

J Kang, N Rui, E Huang, Y Tian, M Mahapatra… - Physical Chemistry …, 2021 - pubs.rsc.org
To activate methane at low or medium temperatures is a difficult task and a pre-requisite for
the conversion of this light alkane into high value chemicals. Herein, we report the …

In situ studies of methane activation using synchrotron-based techniques: Guiding the conversion of C–H bonds

JA Rodriguez, N Rui, F Zhang, SD Senanayake - ACS Catalysis, 2022 - ACS Publications
Methane is a major component in natural gas, and its reforming or conversion to commodity
chemicals (oxygenates, olefins, aromatics) has attracted a lot of attention. While many …