O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts

MM Montemore, MA Van Spronsen, RJ Madix… - Chemical …, 2017 - ACS Publications
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …

Surface science under reaction conditions: CO oxidation on Pt and Pd model catalysts

MA Van Spronsen, JWM Frenken… - Chemical Society …, 2017 - pubs.rsc.org
Platinum and palladium are frequently used as catalytic materials, for example for the
oxidation of CO. This is one of the most widely studied reactions in the field of surface …

Understanding catalyst surfaces during catalysis through near ambient pressure X-ray photoelectron spectroscopy

L Nguyen, FF Tao, Y Tang, J Dou, XJ Bao - Chemical reviews, 2019 - ACS Publications
Heterogeneous catalysis occurs on the surface of a catalyst particle in a gas or liquid
environment of reactants. The surface of the catalyst particle acts as an active chemical …

Present and new frontiers in materials research by ambient pressure x-ray photoelectron spectroscopy

J Schnadt, J Knudsen… - Journal of Physics …, 2020 - iopscience.iop.org
In this topical review we catagorise all ambient pressure x-ray photoelectron spectroscopy
publications that have appeared between the 1970s and the end of 2018 according to their …

Operando surface spectroscopy and microscopy during catalytic reactions: from clusters via nanoparticles to meso‐scale aggregates

G Rupprechter - Small, 2021 - Wiley Online Library
Operando characterization of working catalysts, requiring per definitionem the simultaneous
measurement of catalytic performance, is crucial to identify the relevant catalyst structure …

Ambient pressure photoelectron spectroscopy: Opportunities in catalysis from solids to liquids and introducing time resolution

K Roy, L Artiglia, JA Van Bokhoven - ChemCatChem, 2018 - Wiley Online Library
Photoelectron spectroscopy is an excellent technique to explore chemically complex
systems in catalysis. However, due to a small mean free path of photoelectrons in gas …

Adsorbate-driven reactive interfacial Pt-NiO1−x nanostructure formation on the Pt3Ni(111) alloy surface

J Kim, WH Park, WH Doh, SW Lee, MC Noh… - Science …, 2018 - science.org
The origin of the synergistic catalytic effect between metal catalysts and reducible oxides
has been debated for decades. Clarification of this effect, namely, the strong metal-support …

Adsorbate entropies with complete potential energy sampling in microkinetic modeling

M Jørgensen, H Gronbeck - The Journal of Physical Chemistry C, 2017 - ACS Publications
The influence of different approximations on adsorbate entropies is investigated for density
functional theory based mean-field kinetic modeling. Using CO oxidation over Pt (111) as a …

Lab-based ambient pressure X-ray photoelectron spectroscopy from past to present

C Arble, M Jia, JT Newberg - Surface Science Reports, 2018 - Elsevier
Chemical interactions which occur at a heterogeneous interface between a gas and
substrate are critical in many technological and natural processes. Ambient pressure X-ray …

In Situ DRIFTS and NAP-XPS Exploration of the Complexity of CO2 Hydrogenation over Size-Controlled Pt Nanoparticles Supported on Mesoporous NiO

A Sápi, G Halasi, J Kiss, DG Dobó… - The Journal of …, 2018 - ACS Publications
Pt nanoparticles (4.8 nm) were anchored onto the surface of mesoporous nickel oxide (NiO)
supports. Pt/NiO samples were compared with pristine NiO and Pt/SBA-15 silica catalysts in …