Bottom‐up synthesis of single‐crystalline poly (triazine imide) nanosheets for photocatalytic overall water splitting

Q Wang, G Zhang, W Xing, Z Pan, D Zheng… - Angewandte …, 2023 - Wiley Online Library
Abstract Poly (triazine imide)(PTI/Li+ Cl−), one of the crystalline versions of polymeric carbon
nitrides, holds great promise for photocatalytic overall water splitting. In principle, the …

Improved charge separation in poly (heptazine‐triazine) imides with semi‐coherent interfaces for photocatalytic hydrogen evolution

J Zhang, X Liang, C Zhang, L Lin… - Angewandte Chemie …, 2022 - Wiley Online Library
The construction of heterojunctions is a promising manner to accelerate the separation and
transfer of the charge carriers at the interface. Herein, a binary poly (heptazine‐triazine) …

Rh/Cr2O3 and CoOx Cocatalysts for Efficient Photocatalytic Water Splitting by Poly (Triazine Imide) Crystals

M Liu, G Zhang, X Liang, Z Pan, D Zheng… - Angewandte …, 2023 - Wiley Online Library
In situ photo‐deposition of both Pt and CoOx cocatalysts on the facets of poly (triazine
imide)(PTI) crystals has been developed for photocatalytic overall water splitting. However …

Salt‐melt synthesis of poly heptazine imides with enhanced optical absorption for photocatalytic hydrogen production

M Chang, Z Pan, D Zheng, S Wang, G Zhang… - …, 2023 - Wiley Online Library
Broadening the visible light absorption range and accelerating the separation and migration
process of charge carriers are effective ways to improve photocatalytic quantum efficiencies …

Elucidating the Effect of Crystallinity on the Photoactivity in Poly (heptazine imides)

J Li, J Barrio, Y Fang, Y Pan, M Volokh, S Mondal… - Energy & …, 2023 - ACS Publications
Poly (heptazine imide)(PHI) polymers have been widely studied, owing to their excellent
activity as photocatalysts for various reactions. Their photocatalytic activity has been …

Realigning the melon chains in carbon nitride by rubidium ions to promote photo-reductive activities for hydrogen evolution and environmental remediation

Y Xu, W Shi, Y Zhang, Z Tu, B Sun, Z Wang… - Journal of Hazardous …, 2023 - Elsevier
The photocatalytic efficiency of polymeric carbon nitride (PCN) suffers from unsatisfactory
charge separation because of its amorphous structure. Herein, we report a simple bottom-up …

Molecular Structures of Carbon Nitrides for Photocatalysis

Z Lin, W Lin - Surfaces and Interfaces, 2024 - Elsevier
In the dynamic landscape of artificial photosynthesis research, the recent focus has both on
the inorganic semiconductors and the polymeric materials. Carbon nitrides (CN), with melon …

Carbon Nitrides from Supramolecular Crystals: From Single Atoms to Heterojunctions and Advanced Photoelectrodes

J Barrio, J Li, M Shalom - Chemistry–A European Journal, 2023 - Wiley Online Library
Carbon nitride materials (CN) have become one of the most studied photocatalysts within
the last 15 years. While CN absorbs visible light, its low porosity and fast electron‐hole …

The local ordering of polar solvents around crystalline carbon nitride nanosheets in solution

MC Wilding, C Benmore, TF Headen… - … of the Royal …, 2023 - royalsocietypublishing.org
The crystalline graphitic carbon nitride, poly-triazine imide (PTI) is highly unusual among
layered materials since it is spontaneously soluble in aprotic, polar solvents including …

Amphoteric dissolution of two-dimensional polytriazine imide carbon nitrides in water

K Lisowska, W Purser, F Chang… - … of the Royal …, 2023 - royalsocietypublishing.org
Crystalline two-dimensional carbon nitrides with polytriazine imide (PTI) structure are shown
to act amphoterically, buffering both HCl and NaOH aqueous solutions, resulting in charged …