Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
Iron catalysis in reduction and hydrometalation reactions
D Wei, C Darcel - Chemical reviews, 2018 - ACS Publications
The last two decades have seen an impressive improvement of the use of iron as a
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …
Where silylene–silicon centres matter in the activation of small molecules
Small molecules such as H2, N2, CO, NH3, O2 are ubiquitous stable species and their
activation and role in the formation of value-added products are of fundamental importance …
activation and role in the formation of value-added products are of fundamental importance …
Efficient Photocatalytic Nitrogen Fixation over Cuδ+‐Modified Defective ZnAl‐Layered Double Hydroxide Nanosheets
The photocatalytic reduction of nitrogen (N2) with water (H2O) as the reducing agent holds
great promise as a sustainable future technology for the synthesis of ammonia (NH3) …
great promise as a sustainable future technology for the synthesis of ammonia (NH3) …
Chelating bis-silylenes as powerful ligands to enable unusual low-valent main-group element functions
Conspectus Silylenes are divalent silicon species with an unoccupied 3p orbital and one
lone pair of electrons at the SiII center. Owing to the excellent σ-donating ability of amidinato …
lone pair of electrons at the SiII center. Owing to the excellent σ-donating ability of amidinato …
Isolable Silylene Ligands Can Boost Efficiencies and Selectivities in Metal‐Mediated Catalysis
A significant number of isolable silylenes are currently known. They have quickly developed
from laboratory curiosities to useful ligands in metal‐mediated homogeneous catalysis. This …
from laboratory curiosities to useful ligands in metal‐mediated homogeneous catalysis. This …
A Bis(silylene)‐Substituted ortho‐Carborane as a Superior Ligand in the Nickel‐Catalyzed Amination of Arenes
YP Zhou, S Raoufmoghaddam, T Szilvási… - Angewandte …, 2016 - Wiley Online Library
The synthesis and structure of the first 1, 2‐bis (NHSi)‐substituted ortho‐carborane [(LSi:) C]
2B10H10 (termed SiCCSi) is reported (NHSi= N‐heterocyclic silylene; L= PhC (NtBu) 2). Its …
2B10H10 (termed SiCCSi) is reported (NHSi= N‐heterocyclic silylene; L= PhC (NtBu) 2). Its …
Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms
Monatomic zero-valent silicon and germanium complexes (silylones and germylones),
stabilised by neutral donating ligands, emerged only recently as a new class of low-valent …
stabilised by neutral donating ligands, emerged only recently as a new class of low-valent …
Divalent silicon-assisted activation of dihydrogen in a bis (N-heterocyclic silylene) xanthene nickel (0) complex for efficient catalytic hydrogenation of olefins
The first chelating bis (N-heterocyclic silylene) xanthene ligand [SiII (Xant) SiII] as well as its
Ni complexes [SiII (Xant) SiII] Ni (η2-1, 3-cod) and [SiII (Xant) SiII] Ni (PMe3) 2 were …
Ni complexes [SiII (Xant) SiII] Ni (η2-1, 3-cod) and [SiII (Xant) SiII] Ni (PMe3) 2 were …
N-heterocyclic silylenes as powerful steering ligands in catalysis
The present review highlights the role of N-heterocyclic silylene (NHSi) ligands, the silicon
analogues of N-heterocyclic carbenes (NHCs), utilized in various catalytic organic …
analogues of N-heterocyclic carbenes (NHCs), utilized in various catalytic organic …