Cu (I) complexes–Thermally activated delayed fluorescence. Photophysical approach and material design

R Czerwieniec, MJ Leitl, HHH Homeier… - Coordination Chemistry …, 2016 - Elsevier
Cu (I) complexes often show transitions of distinct metal-to-ligand charge transfer (MLCT)
character. This can lead to small energy separations between the lowest singlet S 1 and …

TADF Material Design: Photophysical Background and Case Studies Focusing on Cu(I) and Ag(I) Complexesa

H Yersin, R Czerwieniec, MZ Shafikov… - … : Materials Based on …, 2018 - Wiley Online Library
Designing of thermally activated delayed fluorescence (TADF) compounds with short TADF
decay time and high emission quantum yield is a challenge. This chapter introduces …

Status and challenges of blue OLEDs: A review

I Siddiqui, S Kumar, YF Tsai, P Gautam, Shahnawaz… - Nanomaterials, 2023 - mdpi.com
Organic light-emitting diodes (OLEDs) have outperformed conventional display technologies
in smartphones, smartwatches, tablets, and televisions while gradually growing to cover a …

Thermally activated delayed fluorescence from Ag (I) complexes: a route to 100% quantum yield at unprecedentedly short decay time

MZ Shafikov, AF Suleymanova, R Czerwieniec… - Inorganic …, 2017 - ACS Publications
The four new Ag (I) complexes Ag (phen)(P2-nCB)(1), Ag (idmp)(P2-nCB)(2), Ag (dmp)(P2-
nCB)(3), and Ag (dbp)(P2-nCB)(4) with P2-nCB= bis (diphenylphosphine)-nido-carborane …

Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes–fast phosphorescence or TADF?

J Nitsch, F Lacemon, A Lorbach, A Eichhorn… - Chemical …, 2016 - pubs.rsc.org
This case study on a series of monomeric, dimeric and polymeric CuI chlorido NHC–picolyl
complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast …

Design strategy for Ag (I)-based thermally activated delayed fluorescence reaching an efficiency breakthrough

MZ Shafikov, AF Suleymanova… - Chemistry of …, 2017 - ACS Publications
A design strategy for the development of Ag (I)-based materials for thermally activated
delayed fluorescence (TADF) is presented. Although Ag (I) complexes usually do not show …

Metal complex based delayed fluorescence materials

G Li, ZQ Zhu, Q Chen, J Li - Organic Electronics, 2019 - Elsevier
This review mainly focuses on the topics related to metal complex based delayed
fluorescence (DF) materials including their molecular design principle, photophysical …

Crystalline metal‐organic materials with thermally activated delayed fluorescence

Z Han, XY Dong, SQ Zang - Advanced Optical Materials, 2021 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) properties of crystalline metal‐organic
materials, mainly including small‐molecule metal–organic complexes, organic ligand …

Dinuclear Ag (I) complex designed for highly efficient thermally activated delayed fluorescence

MZ Shafikov, AF Suleymanova… - The Journal of …, 2018 - ACS Publications
The dinuclear Ag (I) complex has been designed to show thermally activated delayed
fluorescence (TADF) of high efficiency. Strongly electron-donating terminal ligands are …

A strongly greenish-blue-emitting Cu 4 Cl 4 cluster with an efficient spin–orbit coupling (SOC): Fast phosphorescence versus thermally activated delayed fluorescence

XL Chen, R Yu, XY Wu, D Liang, JH Jia… - Chemical …, 2016 - pubs.rsc.org
In this communication, we report a new greenish-blue-emitting Cu (I) complex, Cu4Cl4 (NP)
2, a with high photoluminescence quantum yield of 90% and a short decay time of 9.9 μs …