Olefins are synthetically useful building blocks in modern organic synthesis. Direct
functionalization of olefins; represent one of the most explored transformations in synthetic …

Recent advances in the direct synthesis of trifluoromethyl-containing heterocycles from
trifluoroacetimidoyl chlorides (TFAICs) and derivatives, including …

An alcohol-directed, nickel-catalyzed three-component umpolung carboamination of
unactivated alkenes with aryl/alkenylboronic esters and electrophilic aminating reagents is …

Catalytic carboamination of alkenes is a powerful synthetic tool to access valuable amine
scaffolds from abundant and readily available alkenes. Although a number of synthetic …

A versatile method to access differentially substituted 1, 3-and 1, 4-diamines via nickel-
catalyzed three-component 1, 2-carboamination of alkenyl amines with aryl/alkenylboronic …

A novel and expedient cascade strategy has been demonstrated for the synthesis of fused
benzo‐aza‐oxa‐[5‐6‐5] tetracycles in high yields and diastereoselectivities (up to 20: 1 dr) …

We report herein a three-component 1, 2-arylboration of alkenyl amines bearing a cleavable
picolinamide directing group. With aryl halides as electrophiles and B2Pin2 as nucleophiles …

Comprehensive Summary Directing group‐assisted, transition metal‐catalyzed three‐
component difunctionalization of alkenes has emerged as a powerful tool to drive molecular …

The direct difunctionalization of alkenes is an effective way to construct multiple C–C bonds
in one-pot using a single functional group. The regioselective dicarbofunctionalization of …

We report the development of ureas as sterically undemanding pro-ligands for Pd catalysis.
N-Arylureas outperform phosphine ligands for the Pd-catalyzed heteroannulation of N-tosyl …