Enantioselective radical reactions using chiral catalysts

S Mondal, F Dumur, D Gigmes, MP Sibi… - Chemical …, 2022 - ACS Publications
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

A fruitful decade of organofluorine chemistry: new reagents and reactions

FL Qing, XY Liu, JA Ma, Q Shen, Q Song… - CCS …, 2022 - chinesechemsoc.org
The development of synthetic methods for the introduction of the fluorine atom and
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …

Recent advances in copper-catalysed radical-involved asymmetric 1, 2-difunctionalization of alkenes

ZL Li, GC Fang, QS Gu, XY Liu - Chemical Society Reviews, 2020 - pubs.rsc.org
The radical-involved 1, 2-difunctionalization of alkenes has developed into a robust tool for
preparation of complex organic molecules. Despite significant advances in this area, the …

Ligand development for copper-catalyzed enantioconvergent radical cross-coupling of racemic alkyl halides

XY Dong, ZL Li, QS Gu, XY Liu - Journal of the American Chemical …, 2022 - ACS Publications
The enantioconvergent cross-coupling of racemic alkyl halides represents a powerful tool for
the synthesis of enantioenriched molecules. In this regard, the first-row transition metal …

Copper-catalyzed radical relay for asymmetric radical transformations

F Wang, P Chen, G Liu - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus The direct transformation of C–H bonds into diverse functional groups
represents one of the most atom-and step-economical strategies for organic synthesis and …

Recent updates and future perspectives in aziridine synthesis and reactivity

HJ Dequina, CL Jones, JM Schomaker - Chem, 2023 - cell.com
In this review, selected recent advances in the preparation and reactivity of aziridines using
modern synthetic approaches are highlighted, while comparing these new strategies with …

Advances in synthetic applications of hypervalent iodine compounds

A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Radicals: reactive intermediates with translational potential

M Yan, JC Lo, JT Edwards… - Journal of the American …, 2016 - ACS Publications
This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …

Photoinduced copper-catalyzed asymmetric C–O cross-coupling

J Chen, YJ Liang, PZ Wang, GQ Li… - Journal of the …, 2021 - ACS Publications
The construction of carbon–heteroatom bonds is one of the most active areas of research in
organic chemistry because the function of organic molecules is often derived from the …

Exploiting attractive non-covalent interactions for the enantioselective catalysis of reactions involving radical intermediates

RSJ Proctor, AC Colgan, RJ Phipps - Nature Chemistry, 2020 - nature.com
The past decade has seen unprecedented growth in the development of new chemical
methods that proceed by mechanisms involving radical intermediates. This new attention …