The metal-catalyzed asymmetric conjugate addition (ACA) reaction has emerged as a
general and powerful approach for the construction of optically active compounds and is …

Interelement compounds, that is, compounds containing an interelement bond, 1 are
attractive main group element precursors as these provide the opportunity to transfer both …

An efficient Cu-catalyzed protocol for enantioselective addition of a dimethylphenylsilanyl
group to a wide range of cyclic and acyclic unsaturated ketones, esters, acrylonitriles, and α …

The first rhodium (I)-catalyzed enantioselective Si–H insertion reaction of α-diazoesters and
α-diazophosphonates has been developed. The use of a C 1-symmetric chiral diene ligand …

New reactivities of silylboranes are described with their applications to organic synthesis.
The silylboranes add to unsaturated organic compounds such as alkynes, alkenes, 1, 3 …

The conjugate addition of carbon nucleophiles to acceptor activated olefins is one of the
most important reactions for carbon-carbon bond formation. With optically active metal …

The direct enantioselective 1, 4-addition of water to α, β-unsaturated acceptors is an open
challenge in asymmetric catalysis. Enantioselective conjugate addition of either silicon or …

An efficient nickel/copper‐catalyzed decarbonylative silylation reaction of carboxylic acid
esters with silylboranes is described. This reaction provides access to structurally diverse …

Abstract The Rh-catalyzed asymmetric 1, 4-addition of organometallic reagents to an
appropriate receptor has been a growing area of research over the last decade. The …

Selective double hydroelementation of N-heteroarenes can be one of the most
straightforward and atom-economic routes toward dearomatized N-heterocycles bearing a …