Direct Synthesis of β-Amino Boronates via Amide α-C–H Bond Activation and C(sp3)–C(sp3) Coupling under Dual Ni/Photoredox Catalysis
Z Hu, D Wang, T Xu - ACS Catalysis, 2023 - ACS Publications
Direct transformations of readily available amines or amides via C–H bond functionalization
could provide a fast route for accessing complex molecules. While various groups have …
could provide a fast route for accessing complex molecules. While various groups have …
Access to 1, 2-and 1, 3-Amino Alcohols via Cu-Catalyzed Enantioselective Borylations of Allylamines
A Flaget, C Mazet - Organic Letters, 2024 - ACS Publications
We report Cu-catalyzed enantioselective borylation/oxidation sequences that afford either
enantioenriched 1, 2-or 1, 3-amino alcohols starting from N, N-protected allylamines as a …
enantioenriched 1, 2-or 1, 3-amino alcohols starting from N, N-protected allylamines as a …
Exploring Catalytic Intermediates in Pd-Catalyzed Aerobic Oxidative Amination of 1, 3-Dienes: Multiple Metal Interactions of the Palladium Nanoclusters
K Tabaru, T Fujihara, K Torii, T Suzuki… - Journal of the …, 2024 - ACS Publications
Metal nanoclusters (NCs) have unique properties because of their small size, which makes
them useful as catalysts in reactions like cross-coupling. Pd-catalyzed oxidative amination …
them useful as catalysts in reactions like cross-coupling. Pd-catalyzed oxidative amination …
Silylarylation of Alkenes via meta-Selective C–H Activation of Arenes under Ruthenium/Iron Cooperative Catalysis: Mechanistic Insights from Combined Experimental …
S Neogi, S Bhunya, A Kumar Ghosh, B Sarkar… - ACS …, 2024 - ACS Publications
Organosilicons are privileged skeletons in the domains of pharmaceutical chemistry, organic
synthesis, and materials science. Hence, investigating catalytic techniques for the synthesis …
synthesis, and materials science. Hence, investigating catalytic techniques for the synthesis …
Pd and Fe Cocatalyzed Synthesis of Remotely Borylated Aza-Heterocycles
S Bhatt, AM Nicely, CU Powell, ME Huff… - ACS …, 2024 - ACS Publications
We report the intramolecular 1, n-aminoboration for the simultaneous synthesis of aza-
heterocycles with distal carbon–boron bonds. Pd-catalyzed remote 1, n-aminoboration …
heterocycles with distal carbon–boron bonds. Pd-catalyzed remote 1, n-aminoboration …
Base-Free Borylation of Aryl Halides Enabled by Zn-Promoted Halide Abstraction
Herein, we report the palladium-catalyzed borylation of aryl halides (iodides or bromides)
under base-free conditions utilizing a commercially available Lewis acidic mediator, Zn (OTf) …
under base-free conditions utilizing a commercially available Lewis acidic mediator, Zn (OTf) …
Palladium-Catalyzed 1, 2-Alkynylarylation of Vinyl Arenes with Haloalkynes and Arylboronic Acids
R Ma, S Fang, H Jiang, W Wu - Organic Letters, 2024 - ACS Publications
We herein disclose a novel palladium-catalyzed 1, 2-alkynylarylation of vinyl arenes using
haloalkynes and arylboronic acids as coupling partners. This reaction is characterized by …
haloalkynes and arylboronic acids as coupling partners. This reaction is characterized by …