Recent advances in the structural design and regulation of lanthanide clusters: Formation and self-assembly mechanisms

YL Li, HL Wang, ZH Zhu, FP Liang, HH Zou - Coordination Chemistry …, 2023 - Elsevier
The design and synthesis of lanthanide clusters with novel topological connections and
desirable properties are attracting extensive attention. Researchers have obtained …

Metal borohydrides and derivatives–synthesis, structure and properties

M Paskevicius, LH Jepsen, P Schouwink… - Chemical Society …, 2017 - pubs.rsc.org
A wide variety of metal borohydrides, MBH4, have been discovered and characterized
during the past decade, revealing an extremely rich chemistry including fascinating …

Octacyanidometallates for multifunctional molecule-based materials

S Chorazy, JJ Zakrzewski, M Magott… - Chemical Society …, 2020 - pubs.rsc.org
Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …

High-nuclearity lanthanide-containing clusters as potential molecular magnetic coolers

XY Zheng, XJ Kong, Z Zheng, LS Long… - Accounts of chemical …, 2018 - ACS Publications
Conspectus High-nuclearity cluster-type metal complexes are a unique class of compounds,
many of which have aesthetically pleasing molecular structures. Their interesting physical …

In-situ synthesis of molecular magnetorefrigerant materials

SJ Liu, SD Han, JP Zhao, J Xu, XH Bu - Coordination Chemistry Reviews, 2019 - Elsevier
Zero-dimensional cluster complexes and coordination polymers for magnetic refrigeration
have attracted great interest in the last decade. In-situ synthesis is a widely-used method to …

Ultrastrong Alkali-Resisting Lanthanide-Zeolites Assembled by [Ln60] Nanocages

J Dong, P Cui, PF Shi, P Cheng… - Journal of the American …, 2015 - ACS Publications
Zeolites, as one of the most important porous materials, are most widely utilized in sorbents,
catalysis, and ion-exchange fields. However, the multi-functional lanthanide-zeolites …

Gd(OH)F2: A Promising Cryogenic Magnetic Refrigerant

Q Xu, B Liu, M Ye, G Zhuang, L Long… - Journal of the American …, 2022 - ACS Publications
Magnetic refrigerants with a large magnetocaloric effect (MCE) in a wide temperature range
and low magnetic ordering temperature (T o) in the sub-kelvin temperature region are not …

The Gigantic {Ni36Gd102} Hexagon: A Sulfate-Templated “Star-of-David” for Photocatalytic CO2 Reduction and Magnetic Cooling

WP Chen, PQ Liao, PB Jin, L Zhang… - Journal of the …, 2020 - ACS Publications
Gigantic coordination molecules assembled from a large number of metal ions and organic
ligands are structurally and functionally challenging to characterize. Here we show that a …

Exploring the Performance Improvement of Magnetocaloric Effect Based Gd-Exclusive Cluster Gd60

XM Luo, ZB Hu, Q Lin, W Cheng, JP Cao… - Journal of the …, 2018 - ACS Publications
Despite wide potential applications of Gd-clusters in magnetocaloric effect (MCE) owing to f7
electron configuration of Gd (III), the structural improvement in order to enhance MCE …

Single-molecule magnetism of tetrapyrrole lanthanide compounds with sandwich multiple-decker structures

H Wang, BW Wang, Y Bian, S Gao, J Jiang - Coordination Chemistry …, 2016 - Elsevier
The single-molecule magnetism of sandwich tetrapyrrole lanthanide compounds has clearly
initiated a huge renaissance in the magnetochemistry of pure lanthanide coordination …