Photophysics and photochemistry with Earth-abundant metals–fundamentals and concepts

C Förster, K Heinze - Chemical Society Reviews, 2020 - pubs.rsc.org
Recent exciting developments in the area of mononuclear photoactive complexes with Earth-
abundant metal ions (Cu, Zr, Fe, Cr) for potential eco-friendly applications in …

TADF: Enabling luminescent copper (i) coordination compounds for light-emitting electrochemical cells

CE Housecroft, EC Constable - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The last decade has seen a surge of interest in the emissive behaviour of copper (I)
coordination compounds, both neutral compounds that may have applications in organic …

Organic light emitters exhibiting very fast reverse intersystem crossing

Y Wada, H Nakagawa, S Matsumoto, Y Wakisaka… - Nature …, 2020 - nature.com
Reverse intersystem crossing (RISC), originally considered forbidden in purely organic
materials, has recently become possible by minimizing the energy gap between the lowest …

Eliminating nonradiative decay in Cu (I) emitters:> 99% quantum efficiency and microsecond lifetime

R Hamze, JL Peltier, D Sylvinson, M Jung, J Cardenas… - Science, 2019 - science.org
Luminescent complexes of heavy metals such as iridium, platinum, and ruthenium play an
important role in photocatalysis and energy conversion applications as well as organic light …

“Quick-Silver” from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes

R Hamze, S Shi, SC Kapper… - Journal of the …, 2019 - ACS Publications
A systematic study is presented on the physical and photophysical properties of
isoelectronic and isostructural Cu, Ag, and Au complexes with a common amide (N …

Highly efficient photo-and electroluminescence from two-coordinate Cu (I) complexes featuring nonconventional N-heterocyclic carbenes

S Shi, MC Jung, C Coburn, A Tadle… - Journal of the …, 2019 - ACS Publications
A series of six luminescent two-coordinate Cu (I) complexes were investigated bearing
nonconventional N-heterocyclic carbene ligands, monoamido-aminocarbene (MAC*) and …

Small‐molecule emitters with high quantum efficiency: mechanisms, structures, and applications in OLED devices

Q Wei, N Fei, A Islam, T Lei, L Hong… - Advanced Optical …, 2018 - Wiley Online Library
Organic emitters play a vital role in determining the overall performance of organic light
emitting diode (OLED) devices. Traditional fluorescent emitters can only achieve external …

Cyclic (Amino)(aryl)carbenes Enter the Field of Chromophore Ligands: Expanded π System Leads to Unusually Deep Red Emitting CuI Compounds

M Gernert, L Balles-Wolf, F Kerner… - Journal of the …, 2020 - ACS Publications
A series of copper (I) complexes bearing a cyclic (amino)(aryl) carbene (CAArC) ligand with
various complex geometries have been investigated in great detail with regard to their …

Hybrid thermally activated nanocluster fluorophores for X-ray scintillators

P Yuan, T He, Y Zhou, J Yin, H Zhang, Y Zhang… - ACS Energy …, 2023 - ACS Publications
Thermally activated delayed fluorescence (TADF) X-ray scintillators have attracted
increasing attention because of their theoretical ability to utilize 100% radiation-induced …

Highly Robust CuI‐TADF Emitters for Vacuum‐Deposited OLEDs with Luminance up to 222 200 cd m−2 and Device Lifetimes (LT90) up to 1300 hours at an Initial …

R Tang, S Xu, TL Lam, G Cheng, L Du… - Angewandte Chemie …, 2022 - Wiley Online Library
A critical step in advancing the practical application of copper‐based organic light‐emitting
diodes (OLEDs) is to bridge the large gap between device efficiency and operational …