Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …

This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …

Four 52-metal-ion 3d–4f cluster complexes featuring a common core of Ln42M10 (Ln=
Gd3+, Dy3+; M= Co2+/3+, Ni2+) were obtained through self-assembly of the metal ions …

The hydrolysis of Ln (ClO4) 3 in the presence of acetate leads to the assembly of the three
largest known lanthanide-exclusive cluster complexes,[Nd104 (ClO4) 6 (CH3COO) 60 (μ3 …

Molecular nanomagnets are considered valid candidates for magnetic refrigeration at low
temperatures. Designing these materials for enhanced cooling requires the control and …

The synthesis, structures, and magnetic properties of six families of cobalt–lanthanide mixed-
metal phosphonate complexes are reported in this Article. These six families can be divided …

Two 24-nuclear lanthanide clusters, Gd24 and Dy24 were obtained and structurally
characterized. Magnetic investigations reveal that Gd24 exhibits the largest entropy change …

Molecoolers: An unprecedentedly large cryogenic magnetocaloric effect is observed in
gadolinium acetate tetrahydrate (see picture, Gd pink, O red, C gray). The change in its …

Magnetic refrigeration is based on the magnetocaloric effect (MCE) which relies on the
entropy change of a material when placed in a magnetic field. 1 Molecular magnets have …