Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …

Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

A cyano-bridged Fe (II)–Cr (III) single-chain magnet designed to ensure a parallel
orientation of the axial anisotropy of the building units is reported. This ferromagnetic chain …

A cyanide-bridged Fe2Co 2D sheet exhibiting electron transfer coupled spin transition
(ETCST) with co-existence of magnetic ordering below 50 K is reported. The complex …

Anisotropic magnetic exchange is of great value for the design of high performance
molecular nanomagnets. In the present work, enhanced single‐chain magnet (SCM) …

Abstract Two-dimensional (2D) metal–organic frameworks (MOFs) are the coordination
network of organic cyanide (CN) ligands and metal cyanometallates. They possess great …

We herein report the syntheses, structures, and magnetic properties of two isostructural two-
dimensional (2D) coordination polymers based on a pentagonal bipyramidal CoII unit [Co …

Two-dimensional (2D) coordination polymer (CP)[CoIII (CN) 6] 2 [CoII (TODA)] 3· 7H2O
(TODA= 1, 4, 10-trioxa-7, 13-diazacyclopentadecane, Co-TODA) was reported earlier to …

The introduction of Keggin-type POMs of [PMo12O40] 3–or [SiW12O40] 4–as counteranions
into the FeIII–MII cyanometalate system afforded three chain complexes:[(Tp*) Fe (CN) 3Ni …

Three new cyano-bridged FeII–MoIII complexes assembled from the [MoIII (CN) 7] 4–unit,
FeII ions, and three pentadentate N3O2 ligands, namely {[Fe2H3 (dapab) 2][Mo (CN) 6]} n …