We herein describe a systematic account of mononuclear ruthenium vinyl complexes
L−{Ru}− CH CH− R where the phosphine ligands at the (PR '3) 2Ru (CO) Cl {Ru} moiety, the …

The catalytic properties of several ruthenium, osmium and rhodium hydride complexes for
hydrogen/deuterium (H/D) exchange between olefins and deuterium oxide (D2O) were …

Four divinylphenylene-bridged diruthenium complexes [{Ru (CO)(P i Pr3) 2 (L-κ 2 [N, O]–)} 2
(μ-CH= CH-C6H4-CH= CH-1, 4)](2a–2d) with N, O-chelating 2-hydroxypyridine and 2 …

A series of binuclear ruthenium vinyl complexes with dithienylethene units,[RuCl
(CO)(PMe3) 3] 2 (μ-CH CH-DTE-CH CH)(5a, 5b),[RuCl (CO)(Py)(PPh3) 2] 2 (μ-CH CH …

Treatment of RuHCl (CO)(PPh3) 3 with (E)-HC⋮ CCH CHC⋮ CH produces [RuCl
(CO)(PPh3) 2] 2 (μ-(E, E, E)-CH CHCH CHCH CH). The latter complex reacts with PMe3, 4 …

Four anthracene-based bimetallic ruthenium vinyl complexes, in which two ruthenium units
are attached at different positions (the 9, 10-, 1, 5-, 2, 6-, and 1, 8-positions) of the …

The reactions of the elongated dihydrogen complexes [Os {C6X4C (O) CH3}(η2-
H2)(H2O)(PiPr3) 2] BF4 (X= F, H) with acetylene, cyclohexylacetylene, and phenylacetylene …

Reactions of HC⋮ CCH2CH (OR) CH (OR) CH2C⋮ CH (R= H, MeSO2) with RuHCl
(CO)(PPh3) 3 produced [RuCl (CO)(PPh3) 2] 2 (μ-CH CHCH2CH (OR) CH (OR) CH2CH …

We report the syntheses, electronic properties, and molecular structures of a series of
polychalcogenido-bridged dinuclear uranium species. These complexes are supported by …

Reactions of gold salts with various π-conjugated dialkynes have led to two homologous
series of binuclear alkynylgold (I) complexes, linear rigid-rod Cy3PAu− C≡ C−(CH CH) n …