Organic synthesis using nitroxides
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
Pickering emulsion enhanced interfacial catalysis under Taylor flow in a microchannel reactor
H Li, X Zhang, Q Wang, N Jin, H Wei, Y Zhao - Chemical Engineering …, 2023 - Elsevier
There are still technical challenges associated with surface fouling and clogging in
microchannels when conducting multiphase catalytic reactions involving solid particles. In …
microchannels when conducting multiphase catalytic reactions involving solid particles. In …
Green and continuous aerobic oxidation of ethylbenzene over homogeneous and heterogeneous NHPI in a micro-packed bed reactor
C Zhang, J Luo, B Xie, W Liu, J Zhang - Chemical Engineering Journal, 2023 - Elsevier
Aerobic oxidation of ethylbenzene (EB) has emerged as a promising strategy for the
selective synthesis of acetophenone (AP) in line with green chemistry. The integration of …
selective synthesis of acetophenone (AP) in line with green chemistry. The integration of …
Continuous reductive amination to synthesize primary amines with high selectivity in flow
Reductive amination, a convenient way to convert carbonyl compounds into corresponding
amines, gains increasing attention in the amine production. In this work, we propose a …
amines, gains increasing attention in the amine production. In this work, we propose a …
Green and practical TEMPO-functionalized activated carbon as a durable catalyst for continuous aerobic oxidation of alcohols
C Zhang, M Huang, J Yin, F Lou, X Chen, J Zhang - Journal of Catalysis, 2022 - Elsevier
The development of robust heterogeneous catalysts that can realize the aerobic oxidation of
alcohols in metal-free conditions is a profound challenge. Here, we report a reliable …
alcohols in metal-free conditions is a profound challenge. Here, we report a reliable …
A review on the consequence of 3D-orienation of Cu/TEMPO/imidazole sequence on selective alcohol oxidation
P Chandra - Journal of Molecular Structure, 2023 - Elsevier
The fascinating properties of the naturally occurring biopolymers and enzymes are
benchmark natural materials abetting us to optimize the performance of multifunctional …
benchmark natural materials abetting us to optimize the performance of multifunctional …
A Catecholaldimine-Based NiII-Complex as an Effective Catalyst for the Direct Conversion of Alcohols to trans-Cinnamonitriles and Aldehydes
A nickel (II) complex [Ni (HL) 2] 1 was synthesized by treatment of a new catecholaldimine-
based ligand with NiCl2· 6H2O in methanol at room temperature. Complex 1 showed …
based ligand with NiCl2· 6H2O in methanol at room temperature. Complex 1 showed …
Phosphate-Modified MCM-48-Based Ag Nanoparticle Catalyst for Selective Oxidation of Ethylene Glycol to Glyoxal
W Li, C Liu, Q Yang, Y Ren, H Jiang - ACS Sustainable Chemistry …, 2024 - ACS Publications
Supported silver nanoparticle (Ag NP) catalysts usually have high reactivity for organic
oxidation reactions; however, catalyst deactivation caused by the migration, aggregation …
oxidation reactions; however, catalyst deactivation caused by the migration, aggregation …
Continuous Cu/keto-ABNO catalyzed aerobic oxidation of ethyl lactate to ethyl pyruvate in a micro-packed bed reactor: Process optimization and reaction kinetics
C Zhang, J Luo, B Xie, W Liu, J Zhang - Chemical Engineering Science, 2024 - Elsevier
Pyruvic acid and its esters are increasingly utilized as precursors for synthesizing
antioxidations or dietary supplement in the pharmaceutical industry. The selectivity of …
antioxidations or dietary supplement in the pharmaceutical industry. The selectivity of …
Investigation of External Mass Transfer in a Micropacked Bed Reactor with a Pd/Al2O3/Nickel Foam
L Duan, C Ma, F Lou, J Yin, L Sang… - Industrial & Engineering …, 2022 - ACS Publications
External mass transfer performance of micropacked bed reactors (μPBRs) with
Pd/Al2O3/nickel foam catalysts is investigated by the hydrogenation of α-methylstyrene …
Pd/Al2O3/nickel foam catalysts is investigated by the hydrogenation of α-methylstyrene …