From biomass to vitrimers: Latest developments in the research of lignocellulose, vegetable oil, and naturally-occurring carboxylic acids

Y Yang, H Liu, B Lin, D Tang, J Xu, L Dai… - Industrial Crops and …, 2023 - Elsevier
Thermosets are widely used for their excellent properties, but their permanent cross-linking
makes them difficult to recycle. Covalent adaptive networks can address the recycling of …

[HTML][HTML] Biobased and aromatic Covalent Adaptable Networks: When architectures meet properties, within the framework of a circular bioeconomy

L Sougrati, A Duval, L Avérous - Materials Science and Engineering: R …, 2024 - Elsevier
In the current context of environmental emergency, the need for sustainable materials with
controlled end-of-life is paramount. Covalent Adaptable Networks (CANs) are a novel class …

3D printing of hybrid solid–liquid structures

CM Hsieh, CE Cipriani, EB Pentzer - Polymer International, 2024 - Wiley Online Library
Abstract 3D printing is a versatile technology for creating objects with custom geometries
and compositions and is increasingly employed for fabricating hybrid solid–liquid …

Hybrid Dynamic Covalent Network-Based Protecting Layer for Stable Li-Metal Batteries

H Feng, Y He, M Ma, S Gao, S Zhao… - … Applied Materials & …, 2024 - ACS Publications
Metallic lithium (Li) is considered as the “Holy Grail” anode material for next-generation
energy storage systems due to its extremely high theoretical capacity and low …

Polysquaramides

D Konar, KA Stewart, J Moerschel, JF Rynk… - ACS Macro …, 2024 - ACS Publications
Thermoplastics, while advantageous for their processability and recyclability, often
compromise thermochemical stability and mechanical strength compared to thermosets …

Biobased Polystyrene Vitrimers for Thermoset Circularity

KA Stewart, TH Le, NB Wei, AJ Cantor… - ACS Applied Polymer …, 2024 - ACS Publications
Thermoset polymers, known for their robust thermomechanical and chemical durability,
suffer from poor recyclability due to their covalent cross-linking. This study explores the …

Tuning the Mechanical and Dynamic Properties of Elastic Vitrimers by Tailoring the Substituents of Boronic Ester

Z Demchuk, X Zhao, Z Shen, S Zhao… - ACS Materials …, 2023 - ACS Publications
Elastic vitrimers, ie, elastic polymers with associative dynamic covalent bonds, can afford
elastomers with recyclability while maintaining their thermal and chemical stability. Herein …

Closing the loop: polyimine thermosets from furfural derived bioresources

T Türel, K Saito, I Glišić, T Middelhoek… - RSC Applied …, 2024 - pubs.rsc.org
Over the past few decades, thermosetting plastics have emerged as indispensable materials
in both industrial applications and our daily lives, primarily due to their exceptional thermal …

Mild synthesis of 2, 3, 5, 6-tetrafluoropyridine ethers and their reactivity toward imidazole and pyrazole

NJ Weeks, KD Kramer, NW Surina, TJ Fuhrer… - Journal of Fluorine …, 2024 - Elsevier
A series of six, 4-substituted 2, 3, 5, 6-tetrafluoropyridine (TFP) hetero ethers have been
synthesized via regio-selective, nucleophilic aromatic substitution (SNAr) of …

Comparison of the ablative performance of silicone rubber‐based composites by analyzing a large number of samples

H Zhang, C Zhou, Z Lu, Y Tian, J Tian, X Chi… - Journal of Applied … - Wiley Online Library
Silicone rubber‐based materials are important thermal protection materials for high‐
temperature applications. In this work, a holistic analysis of silicone rubber‐based materials …