Influence of functional groups on low-temperature combustion chemistry of biofuels

B Rotavera, CA Taatjes - Progress in Energy and Combustion Science, 2021 - Elsevier
Ongoing progress in synthetic biology, metabolic engineering, and catalysis continues to
produce a diverse array of advanced biofuels with complex molecular structure and …

Chemical kinetics of cyclic ethers in combustion

LS Tran, O Herbinet, HH Carstensen… - Progress in Energy and …, 2022 - Elsevier
Abstract Cyclic Ethers (CEs) belong to a class of compounds of importance to understand
the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of …

Effects of oxygenated fuel pertaining to fuel analysis on diesel engine combustion and emission characteristics

MK Rahiman, S Santhoshkumar, D Subramaniam… - Energy, 2022 - Elsevier
The fossil fuel concerns pertaining to the cost augmentation, depletion and environmental
issues needs to be supported by alternative fuel. This work reports the suitability of tri-fuel …

Higher alcohol and ether biofuels for compression-ignition engine application: a review with emphasis on combustion kinetics

L Cai, F vom Lehn, H Pitsch - Energy & Fuels, 2021 - ACS Publications
High molecular weight alcohol and ether fuels with their advanced autoignition propensities
and oxygenated molecular structures are promising future fuel candidates for compression …

Lowering of reaction rates by energetically favorable hydrogen bonding in the transition state. degradation of biofuel ketohydroperoxides by OH

L Xing, L Lian, Z Wang, Z Cheng, Y He… - Journal of the …, 2022 - ACS Publications
Ketohydroperoxides (KHPs) are oxygenates with carbonyl and hydroperoxy functional
groups, and they are generated under combustion and atmospheric conditions. Their fate is …

Experimental characterization of n-heptane low-temperature oxidation products including keto-hydroperoxides and highly oxygenated organic molecules (HOMs)

N Belhadj, R Benoit, P Dagaut, M Lailliau - Combustion and Flame, 2021 - Elsevier
The oxidation of n-heptane was performed in a jet-stirred reactor (JSR) at 10 atm, an
equivalence ratio of 0.5, and an initial fuel concentration of 1000 ppm at a residence time of …

Experimental and kinetic modeling study of n-hexane oxidation. Detection of complex low-temperature products using high-resolution mass spectrometry

N Belhadj, M Lailliau, R Benoit, P Dagaut - Combustion and Flame, 2021 - Elsevier
This study concerns the oxidation of n-hexane. It was conducted in continuous flow fused-
silica jet-stirred reactor (JSR) at 10 atm and an equivalence ratio of 0.5. n-Hexane initial …

[HTML][HTML] A chemical kinetic study of tetrahydropyran high-pressure oxidation in a jet-stirred reactor

B Hoblos, Z Serinyel, G Dayma, P Dagaut - Combustion and Flame, 2024 - Elsevier
Cyclic ethers are commonly formed as intermediates during the low-temperature oxidation of
hydrocarbons. Tetrahydropyran (THP) is one of the most important cyclic ethers, recently …

[HTML][HTML] Properties and Autoignition Reactivity of Diesel Boiling Range Ethers Produced from Guerbet Alcohols

RL McCormick, J Luecke, SY Mohamed, GM Fioroni… - Fuel …, 2024 - Elsevier
We examine the properties of diesel boiling range ethers made from coupling of alcohols
produced by oligomerization of ethanol (Guerbet alcohols) for their utility as low-carbon …

Experimental characterization of tetrahydrofuran low-temperature oxidation products including ketohydroperoxides and highly oxygenated molecules

N Belhadj, R Benoit, P Dagaut, M Lailliau - Energy & Fuels, 2020 - ACS Publications
The oxidation of tetrahydrofuran (THF) was carried out in a continuously jet-stirred tank
reactor at a total pressure of 10 atm, in fuel-lean conditions (equivalence ratio= 0.5), at an …