Molecular magnetic materials based on 4d and 5d transition metals

XY Wang, C Avendaño, KR Dunbar - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

A toolbox of building blocks, linkers and crystallisation methods used to generate single-chain magnets

S Dhers, HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets (SMMs) and single-chain magnets (SCMs) are potential
candidates for more dense data storage and quantum computing as well as providing …

[HTML][HTML] Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

The Shrinking World of Innocent Ligands: Conventionaland Non‐Conventional Redox‐Active Ligands

W Kaim - 2012 - Wiley Online Library
This essay for EurJIC's cluster issue on cooperative and redox non‐innocent ligands
introduces the reader to redox‐active ligands, which range from the small archetypical …

[ReF6]2−: A Robust Module for the Design of Molecule‐Based Magnetic Materials

KS Pedersen, M Sigrist, MA Sørensen… - Angewandte Chemie …, 2014 - Wiley Online Library
A facile synthesis of the [ReF6] 2− ion and its use as a building block to synthesize magnetic
systems are reported. Using dc and ac magnetic susceptibility measurements, INS and EPR …

A Uranium‐Based UO2+–Mn2+ Single‐Chain Magnet Assembled trough Cation–Cation Interactions

V Mougel, L Chatelain, J Hermle, R Caciuffo… - Angewandte …, 2014 - Wiley Online Library
Single‐chain magnets (SCMs) are materials composed of magnetically isolated one‐
dimensional (1D) units exhibiting slow relaxation of magnetization. The occurrence of SCM …

Single-chain magnets assembled in cobalt (ii) metal–organic frameworks

M Wang, X Gou, W Shi, P Cheng - Chemical communications, 2019 - pubs.rsc.org
Single-chain magnets (SCMs) are one-dimensional (1D) coordination polymers that exhibit
magnetic bistability and have potential application in high-density information processing …

Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Utility of redox-active ligands for reversible multi-electron transfer in uranyl (vi) complexes

T Takeyama, S Tsushima, K Takao - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
In most cases, the redox activity of a UVIO22+ complex is regarded as metal-centered
phenomena, because uranium has small energy gaps amongst the 5f/6d/7s subshells …

Two field-induced slow magnetic relaxation processes in a mononuclear Co (II) complex with a distorted octahedral geometry

J Li, Y Han, F Cao, RM Wei, YQ Zhang, Y Song - Dalton Transactions, 2016 - pubs.rsc.org
A distorted octahedral CoII complex is reported with homoscorpionate ligands. This complex
comprised a field-induced single-molecule magnet, showing two slow relaxation processes …