Synergistic dual transition metal catalysis

UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Palladium-catalyzed cross-coupling reactions: a powerful tool for the synthesis of agrochemicals

P Devendar, RY Qu, WM Kang, B He… - Journal of agricultural …, 2018 - ACS Publications
Pd-catalyzed cross-coupling reactions have become essential tools for the construction of
carbon–carbon and carbon–heteroatom bonds. Over the last three decades, great efforts …

Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation

B Zhao, T Rogge, L Ackermann, Z Shi - Chemical Society Reviews, 2021 - pubs.rsc.org
The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Decarboxylative reactions with and without light–a comparison

J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

Palladium‐catalyzed cross‐coupling: a historical contextual perspective to the 2010 Nobel Prize

CCC Johansson Seechurn, MO Kitching… - Angewandte Chemie …, 2012 - Wiley Online Library
Abstract In 2010, Richard Heck, Ei‐ichi Negishi, and Akira Suzuki joined the prestigious
circle of Nobel Laureate chemists for their roles in discovering and developing highly …

Direct C− H transformation via iron catalysis

CL Sun, BJ Li, ZJ Shi - Chemical Reviews, 2011 - ACS Publications
The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

Total Synthesis of Aryl C-Glycoside Natural Products: Strategies and Tactics

K Kitamura, Y Ando, T Matsumoto, K Suzuki - Chemical reviews, 2018 - ACS Publications
The aryl C-glycoside structure is, among the plenty of biologically active natural products,
one of the distinct motifs embedded. Because of the potential bioactivity as well as the …

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

N Rodríguez, LJ Goossen - Chemical Society Reviews, 2011 - pubs.rsc.org
This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …

Design and optimization of catalysts based on mechanistic insights derived from quantum chemical reaction modeling

S Ahn, M Hong, M Sundararajan, DH Ess… - Chemical …, 2019 - ACS Publications
Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …

Tosylhydrazones: new uses for classic reagents in palladium‐catalyzed cross‐coupling and metal‐free reactions

J Barluenga, C Valdés - Angewandte Chemie International …, 2011 - Wiley Online Library
Tosylhydrazones are useful synthetic intermediates that have been used in organic
chemistry for almost 60 years. The recent discovery of a palladium‐catalyzed cross‐coupling …