Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

The high utility of halogenated organic compounds has prompted the development of a vast
number of transformations which install the carbon–halogen motif. Traditional routes to …

Electrophilic aminating reagents have seen a renaissance in recent years as effective
nitrogen sources for the synthesis of unprotected amino functionalities. Based on their …

Primary amines are essential constituents of biologically active molecules and versatile
intermediates in the synthesis of drugs and agrochemicals. However, their preparation from …

Alkenes are versatile building blocks in modern organic synthesis. In the difunctionalization
reactions of alkenes, two functional groups can be simultaneously introduced into the π …

Nitrene transfer reactions are powerful tools in synthetic organic chemistry. In recent years,
transition-metal catalyzed nitrene transfer reactions with carbamates as the nitrene …

The introduction of nitrogen atoms into small molecules is of fundamental importance and it
is vital that ever more efficient and selective methods for achieving this are developed. With …

We herein report a new catalytic method for intermolecular olefin aminofluorination using
earth-abundant iron catalysts and nucleophilic fluoride ion. This method tolerates a broad …

Recent progress on catalytic nitrene transfer reactions with hydroxylamine derivatives as
prevalent precursors is summarized in this highlight. The salient features of these N–O …

Analyzing and measuring different macromolecules demands the use of
chemiluminescence (CL) techniques. Several CL agents are available, with different …