Activation of Si–H and B–H bonds by Lewis acidic transition metals and p-block elements: same, but different
P Ríos, A Rodríguez, S Conejero - Chemical Science, 2022 - pubs.rsc.org
In this Perspective we discuss the ability of transition metal complexes to activate and cleave
the Si–H and B–H bonds of hydrosilanes and hydroboranes (tri-and tetra-coordinated) in an …
the Si–H and B–H bonds of hydrosilanes and hydroboranes (tri-and tetra-coordinated) in an …
Hydrosilylation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η1-Silane Iridium(III) Complex
S Park, M Brookhart - Organometallics, 2010 - ACS Publications
Hydrosilylation of a variety of ketones and aldehydes using the cationic iridium catalyst
(POCOP) Ir (H)(acetone)+, 1 (POCOP= 2, 6-bis (di-tert-butylphosphinito) phenyl), is reported …
(POCOP) Ir (H)(acetone)+, 1 (POCOP= 2, 6-bis (di-tert-butylphosphinito) phenyl), is reported …
Hydrosilylation Reactions Catalyzed by Rhenium
Hydrosilylation is an important process, not only in the silicon industry to produce silicon
polymers, but also in fine chemistry. In this review, the development of rhenium-based …
polymers, but also in fine chemistry. In this review, the development of rhenium-based …
Analysis of an unprecedented mechanism for the catalytic hydrosilylation of carbonyl compounds
This work details an in-depth evaluation of an unprecedented mechanism for the
hydrosilylation of carbonyl compounds catalyzed by (PPh3) 2Re (O) 2I. The proposed …
hydrosilylation of carbonyl compounds catalyzed by (PPh3) 2Re (O) 2I. The proposed …
Enantioselective Reduction of Ketones and Imines Catalyzed by (CN‐Box)ReV–Oxo Complexes
The development and application of chiral, non‐racemic ReV–oxo complexes to the
enantioselective reduction of prochiral ketones is described. In addition to the …
enantioselective reduction of prochiral ketones is described. In addition to the …
Mechanistic Insight into Hydrosilylation Reactions Catalyzed by High Valent Re⋮ X (X= O, NAr, or N) Complexes: The Silane (Si H) Does Not Add across the Metal …
G Du, PE Fanwick, MM Abu-Omar - Journal of the American …, 2007 - ACS Publications
Treatment of oxo and imido-rhenium (V) complexes Re (X) Cl3 (PR3) 2 (X= O, NAr, and R=
Ph or Cy)(1− 2) with Et3SiH affords Re (X) Cl2 (H)(PR3) 2 in high yields. Cycloaddition of …
Ph or Cy)(1− 2) with Et3SiH affords Re (X) Cl2 (H)(PR3) 2 in high yields. Cycloaddition of …
E–H (E= B, Si, Ge) bond activation of pinacolborane, silanes, and germanes by nucleophilic palladium carbene complexes
CC Comanescu, VM Iluc - Chemical Communications, 2016 - pubs.rsc.org
The reactivity of two nucleophilic palladium carbenes,[PC (sp2) P] Pd (PMe3) and [PC (sp2)
P] Pd (PPh3), where [PC (sp2) P]= bis [2-(di-iso-propylphosphino) phenyl] methylene …
P] Pd (PPh3), where [PC (sp2) P]= bis [2-(di-iso-propylphosphino) phenyl] methylene …
Catalytic hydrosilylation of carbonyl compounds with cationic oxorhenium (V) salen
G Du, MM Abu-Omar - Organometallics, 2006 - ACS Publications
High-valent cationic oxorhenium (V) salen complexes efficiently catalyze the reduction of
carbonyl compounds by organosilanes under mild, open-flask conditions. Good to excellent …
carbonyl compounds by organosilanes under mild, open-flask conditions. Good to excellent …
Rhenium-Catalyzed Reduction of Carboxylic Acids with Hydrosilanes
Re2 (CO) 10 efficiently catalyzes the direct reduction of various carboxylic acids under mild
conditions (rt, irradiation 350 or 395 nm). While aliphatic carboxylic acids were readily …
conditions (rt, irradiation 350 or 395 nm). While aliphatic carboxylic acids were readily …
Oxo and imido complexes of rhenium and molybdenum in catalytic reductions
G Du, MM Abu-Omar - Current Organic Chemistry, 2008 - ingentaconnect.com
High oxidation state transition metal oxo and imido complexes are ubiquitous in catalytic
oxidations and oxygen atom transfer reactions. Recently these complexes, particularly those …
oxidations and oxygen atom transfer reactions. Recently these complexes, particularly those …