Bio-inspired mononuclear nonheme metal peroxo complexes: Synthesis, structures and mechanistic studies toward understanding enzymatic reactions
D Jeong, JS Valentine, J Cho - Coordination Chemistry Reviews, 2023 - Elsevier
Metalloenzymes utilize inexpensive and earth-abundant transition metal ions as important
co-factors to enable binding of a dioxygen molecule so that it can be used in various …
co-factors to enable binding of a dioxygen molecule so that it can be used in various …
Negative catalysis/non-Bell-Evans-Polanyi reactivity by metalloenzymes: Examples from mononuclear heme and non-heme iron oxygenases
There are many examples in bioinorganic chemistry, where metalloenzymes produce
different reaction products than analogous biomimetic model complexes despite them …
different reaction products than analogous biomimetic model complexes despite them …
A comprehensive insight into aldehyde deformylation: mechanistic implications from biology and chemistry
Aldehyde deformylation is an important reaction in biology, organic chemistry and inorganic
chemistry and the process has been widely applied and utilized. For instance, in biology, the …
chemistry and the process has been widely applied and utilized. For instance, in biology, the …
A Mononuclear Non-Heme Iron (III)–Peroxo Complex with an Unprecedented High O–O Stretch and Electrophilic Reactivity
A mononuclear non-heme iron (III)–peroxo complex,[Fe (III)(O2)(13-TMC)]+(1), was
synthesized and characterized spectroscopically; the characterization with electron …
synthesized and characterized spectroscopically; the characterization with electron …
Appended Lewis Acids Enable Dioxygen Reactivity and Catalytic Oxidations with Ni (II)
DM Beagan, C Rivera… - Journal of the American …, 2024 - ACS Publications
We disclose a suite of Ni (II) complexes featuring secondary sphere Lewis acids of varied
Lewis acidity and tether lengths. Several of these complexes feature atypical behavior of Ni …
Lewis acidity and tether lengths. Several of these complexes feature atypical behavior of Ni …
Eccentricities in Spectroscopy and Reactivity of Non‐Heme Metal Intermediates Contained in Bispidine Scaffolds
G Mukherjee, CV Sastri - Israel Journal of Chemistry, 2020 - Wiley Online Library
Ligand framework in a metal complex has a pivotal role to play in orchestrating the
spectroscopic and reactivity parameters. High‐valent non‐heme metal intermediates are …
spectroscopic and reactivity parameters. High‐valent non‐heme metal intermediates are …