Chiroptical properties of symmetric double, triple, and multiple helicenes

T Mori - Chemical Reviews, 2021 - ACS Publications
Helicenes have attracted considerable attention due to their inherent helical chirality and
extended π-conjugation. Recently, rapid progress has been witnessed in the preparation of …

Enantioenriched helicenes and helicenoids containing main-group elements (B, Si, N, P)

K Dhbaibi, L Favereau, J Crassous - Chemical reviews, 2019 - ACS Publications
In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-
group elements. Enantioenriched helicenic derivatives containing main-group elements B …

Aromaticity of metallabenzenes and related compounds

I Fernández, G Frenking, G Merino - Chemical Society Reviews, 2015 - pubs.rsc.org
The concept of aromaticity was initially introduced in chemistry to account for the stability,
reactivity, molecular structures, and other properties of many unsaturated organic …

Helicene-based transition metal complexes: synthesis, properties and applications

N Saleh, C Shen, J Crassous - Chemical Science, 2014 - pubs.rsc.org
The coordination and/or organometallic chemistry of π-helicenic ligands is a powerful tool to
generate multifunctional molecules displaying optimized chiroptical properties combined …

Acid/base‐triggered switching of circularly polarized luminescence and electronic circular dichroism in organic and organometallic helicenes

N Saleh, B Moore, M Srebro… - … A European Journal, 2015 - Wiley Online Library
Electronic circular dichroism and circularly polarized luminescence acid/base switching
activity has been demonstrated in helicene‐bipyridine proligand 1 a and in its “rollover” …

Recent development in the chemistry of transition metal-containing metallabenzenes and metallabenzynes

J Chen, G Jia - Coordination Chemistry Reviews, 2013 - Elsevier
Transition metal-containing metallabenzenes and metallabenzynes are organometallic
compounds derived from formal replacement of a CH group or a C atom in benzene and …

Straightforward access to mono-and bis-cycloplatinated helicenes displaying circularly polarized phosphorescence by using crystallization resolution methods

C Shen, E Anger, M Srebro, N Vanthuyne, KK Deol… - Chemical …, 2014 - pubs.rsc.org
Enantiopure mono-cycloplatinated-[8] helicene and bis-cycloplatinated-[6] helicene
derivatives were prepared through column chromatography combined with crystallization of …

Application of the five-membered ring blue light-emitting iridium products of cyclometalation reactions as OLEDs

I Omae - Coordination Chemistry Reviews, 2016 - Elsevier
Organic light-emitting diodes (OLEDs) are manufactured primarily by synthesizing five-
membered ring products using cyclometalation reactions. Highly photoluminescent quantum …

Chiral multifunctional molecules based on organometallic helicenes: recent advances

J OuYang, J Crassous - Coordination Chemistry Reviews, 2018 - Elsevier
Organometallic chemistry of helicenes ligands has received great attention and can be
considered as a useful tool for the development of chiral multifunctional molecules …

Synthesis and chiroptical properties of hexa‐, octa‐, and deca‐azaborahelicenes: influence of helicene size and of the number of boron atoms

C Shen, M Srebro‐Hooper, M Jean… - … A European Journal, 2017 - Wiley Online Library
Four members of a new class of cycloborylated hexa‐, octa‐, and deca‐helicenes (1 a–d)
have been prepared in enantiopure form, along with two cycloplatinated deca‐helicenes (1 …