N-heterocyclic carbene transition metal complexes for catalysis in aqueous media
HD Velazquez, F Verpoort - Chemical Society Reviews, 2012 - pubs.rsc.org
The last decade has seen an increasing number of reports on the use of NHC–metal
complexes for catalysis in water, therefore this review is aimed to introduce the whole …
complexes for catalysis in water, therefore this review is aimed to introduce the whole …
Synthesis and application of water‐soluble NHC transition‐metal complexes
LA Schaper, SJ Hock, WA Herrmann… - Angewandte Chemie …, 2013 - Wiley Online Library
We provide an overview on the state‐of‐the‐art in transition‐metal complexes formed with
water‐soluble NHC ligands. Paths to introducing water solubility by ligand design are …
water‐soluble NHC ligands. Paths to introducing water solubility by ligand design are …
Water in N-heterocyclic carbene-assisted catalysis
Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …
Rhodium and iridium complexes of N-heterocyclic carbenes via transmetalation: Structure and dynamics
AR Chianese, X Li, MC Janzen, JW Faller… - …, 2003 - ACS Publications
Rhodium and iridium complexes of N-heterocyclic carbenes (3a− c and 4a− c) were
obtained by transmetalation from the corresponding Ag (I) complexes. The structure of 3b …
obtained by transmetalation from the corresponding Ag (I) complexes. The structure of 3b …
Hydrophilic ligands and their application in aqueous-phase metal-catalyzed reactions
KH Shaughnessy - Chemical reviews, 2009 - ACS Publications
Water is truly ubiquitous. Approximately 80% of the earth's surface is covered by water,
although only 1% of this is drinkable water. Water is the solvent of life and makes up about …
although only 1% of this is drinkable water. Water is the solvent of life and makes up about …
Glycerol and derived solvents: new sustainable reaction media for organic synthesis
AE Díaz-Álvarez, J Francos, B Lastra-Barreira… - Chemical …, 2011 - pubs.rsc.org
The rapid growth of the biodiesel industry has led to a large surplus of its major byproduct, ie
glycerol, for which new applications need to be found. Research efforts in this area have …
glycerol, for which new applications need to be found. Research efforts in this area have …
Stabilization of Organometallic Species Achieved by the Use of N‐Heterocyclic Carbene (NHC) Ligands
NM Scott, SP Nolan - European journal of inorganic chemistry, 2005 - Wiley Online Library
This review describes the stabilization of various coordinatively unsaturated metal centers
through the incorporation of N‐heterocyclic carbene (NHC) ligands. Such species are more …
through the incorporation of N‐heterocyclic carbene (NHC) ligands. Such species are more …
Palladium-catalyzed cross-coupling in aqueous media: recent progress and current applications
KH Shaughnessy, RB DeVasher - Current Organic Chemistry, 2005 - ingentaconnect.com
Water has attracted significant attention as an alternative solvent for homogeneous metal-
catalyzed reactions because it is a non-toxic, nonflammable solvent that can allow for …
catalyzed reactions because it is a non-toxic, nonflammable solvent that can allow for …
Novel sulfonated N-heterocyclic carbene gold (I) complexes: Homogeneous gold catalysis for the hydration of terminal alkynes in aqueous media
A Almássy, CE Nagy, AC Bényei, F Joó - Organometallics, 2010 - ACS Publications
A series of novel water-soluble AuI complexes using sulfonated N-heterocyclic
imidazolylidene carbenes as ligands was prepared by transmetalation from the …
imidazolylidene carbenes as ligands was prepared by transmetalation from the …
Facile Synthesis of [(NHC) MX (Cod)] and [(NHC) MCl (CO) 2](M= Rh, Ir; X= Cl, I) Complexes
R Savka, H Plenio - Dalton Transactions, 2015 - pubs.rsc.org
Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO) 2 ] (M = Rh, Ir; X = Cl, I) complexes -
Dalton Transactions (RSC Publishing) DOI:10.1039/C4DT03449J Royal Society of Chemistry …
Dalton Transactions (RSC Publishing) DOI:10.1039/C4DT03449J Royal Society of Chemistry …