Four-coordinate organoboron derivatives present interesting chemical, physical, biological,
electronical, and optical properties. Given the increasing demand for the synthesis of smart …

The studies published over the last 15 years on the synthesis, physicochemical properties,
and application prospects of saturated and unsaturated three-and four-membered boron …

An acid-mediated rapid synthesis of α-aryl azahelicenes via C–C bond cleavage of helical 9
H-fluoren-9-ols is reported. The newly introduced aryl ring and pyridine moieties provide an …

NBN‐and BNB‐doped phenalenyls are isoelectronic to phenalenyl anions and cations,
respectively. They represent a pair of complementary molecules that have essentially …

Photoinduced synthetic approaches to organoboron compounds have attracted significant
attention in the recent years. Photochemical activation of organic molecules enables …

Abstract B (npy) Ar2 (npy= 2‐(naphthalen‐1‐yl) pyridine) compounds bearing various
nonbulky aryl groups undergo a clean and sequential two‐step photoisomerization in which …

Enantioenriched boron chelates show promising synthetic and luminescent properties;
however, the challenging synthesis makes these compounds scarce. In our earlier work, we …

Molecules stereogenic only at tetrahedral boron atoms show great promise for applications,
for example as chiroptical materials, but are scarcely investigated due to their synthetic …

A computational model for the palladium-catalyzed C–H functionalization of thiophenes with
aluminum hydride reagents has been developed. This model predicts that metalation should …

Stereogenic main group elements are clearly generating interest in the enantioselective
catalysis field. Surprisingly, while chiral organoboron reagents are very useful in …