Tris (pyridyl) borates: an emergent class of versatile and robust polydentate ligands for catalysis and materials applications

J McQuade, F Jäkle - Dalton Transactions, 2023 - pubs.rsc.org
Tridentate ligands that incorporate pyridyl rather than pyrazolyl groups are emerging as an
attractive class of “scorpionate”-type ligands with enhanced electron donation, increased …

Copper (I), silver (I), and gold (I) ethylene complexes of fluorinated and boron-methylated bis-and tris (pyridyl) borate chelators

BT Watson, M Vanga, A Noonikara-Poyil… - Inorganic …, 2023 - ACS Publications
Bis-and tris-pyridyl borate ligands containing pyridyl donor arms, a methylated boron cap,
and a fluorine-lined coordination pocket have been prepared and utilized in coinage metal …

[HTML][HTML] The Tripodal Ligand's 4f Complexes: Use in Molecular Magnetism

KE Vostrikova - Inorganics, 2023 - mdpi.com
A predictable type of coordination is a key property of tripodal ligands. Homo-and
heteroleptic lanthanide complexes with tripodal ligands are a representative class of …

Ethylene polymerization with thermally robust vanadium (III) tris (2-pyridyl) borate complexes

J Qian, RJ Comito - Organometallics, 2023 - ACS Publications
Despite the useful selectivity offered by vanadium catalysts for olefin polymerization, their
implementation under practical conditions remains limited by poor productivity and thermal …

Carbonyl and Isocyanide Complexes of Copper and Silver Supported by Fluorinated Poly (pyridyl) borates

M Vanga, A Noonikara-Poyil, J Wu, HVR Dias - Organometallics, 2022 - ACS Publications
The pyridine-based poly (pyridyl) borates are a recent addition to the scorpionate family.
Furthermore, pyridyl ring substituted analogues are also rare. The synthesis of a bis (pyridyl) …

Multicolor Adjustable B–N Molecular Switches: Simple, Efficient, Portable, and Visual Identification of Butanol Isomers

Y Sun, H Ding, M Tang, J Wen, S Yue, Y Peng… - Analytical …, 2023 - ACS Publications
As intelligent probes, dynamic and controllable molecular switches are useful tools for
probing and intervening in life processes. However, the types and properties of molecular …

Aluminum Tris (2-pyridyl) borates: Structure, reactivity and catalysis

J Qian, S Simran, RJ Comito - Polyhedron, 2024 - Elsevier
Abstract Tris (2-pyridyl) borates are emerging scorpionate ligands distinguished by their
robustness and modularity, as well as their strong electron-donicity. Metal tris (2-pyridyl) …

A Selenenium-Bridged 10-Boratriptycene Lewis Acid

A Osi, N Tumanov, J Wouters, A Chardon… - Synthesis, 2023 - thieme-connect.com
A non-planar triarylborane and a new member of the boratriptycene family bearing a
selenium atom in bridgehead position of triptycene scaffold was generated and isolated as a …

Lanthanide Complexes with Tripodal Ligands

KE Vostrikova - 2023 - preprints.org
The main property of tripodal ligands is the predictable type of coordination. Homo-and
heteroleptic lanthanide complexes with tripodal ligands are a representative class of …