[HTML][HTML] New achievements on CC bond formation in water catalyzed by metal complexes

F Scalambra, P Lorenzo-Luis, I de los Rios… - Coordination Chemistry …, 2021 - Elsevier
The C–C coupling is the best strategy to obtain new organic molecules and building blocks
from economical and abundant small molecules. Traditionally these reactions are …

Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations

SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …

Functionalization of ruthenium olefin-metathesis catalysts for interdisciplinary studies in chemistry and biology

T Matsuo - Catalysts, 2021 - mdpi.com
Hoveyda–Grubbs-type complexes, ruthenium catalysts for olefin metathesis, have gained
increased interest as a research target in the interdisciplinary research fields of chemistry …

Degradable vinyl copolymer nanoparticles/latexes by aqueous nitroxide-mediated polymerization-induced self-assembly

M Lages, N Gil, P Galanopoulo, J Mougin… - …, 2022 - ACS Publications
The synthesis of degradable vinyl polymer nanoparticles/latexes in aqueous dispersed
media is receiving much attention, particularly for biomedical applications and plastic …

Air-stable single-component Pd-catalysts for vinyl-addition polymerization of functionalized norbornenes

EV Bermesheva, EI Medentseva, AP Khrychikova… - ACS …, 2022 - ACS Publications
Well-defined single-component and tolerant Ru-, Mo-, and W-catalysts have been earlier
developed for ring-opening metathesis polymerization of norbornene and its derivatives …

Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium− Carbene Catalysts

DL Nascimento, M Foscato, G Occhipinti… - Journal of the …, 2021 - ACS Publications
Bimolecular catalyst decomposition is a fundamental, long-standing challenge in olefin
metathesis. Emerging ruthenium–cyclic (alkyl)(amino) carbene (CAAC) catalysts, which …

Water-accelerated decomposition of olefin metathesis catalysts

CO Blanco, DE Fogg - ACS catalysis, 2023 - ACS Publications
Water is ubiquitous in olefin metathesis, at levels ranging from contaminant to cosolvent. It is
also non-benign. Water-promoted catalyst decomposition competes with metathesis, even …

Solvent effects in grafting-through ring-opening metathesis polymerization

SE Blosch, M Alaboalirat, CB Eades… - …, 2022 - ACS Publications
Ring-opening metathesis polymerization (ROMP) utilizing Grubbs' third-generation catalyst
((H2IMes)(Cl) 2 (pyr) 2RuCHPh) shows the characteristics of living polymerizations …

Monomer Emulsified Aqueous Ring-Opening Metathesis Polymerization (ME-ROMP) for the Synthesis of Water-Soluble Molecular Bottlebrushes with a Precise …

W Hou, Y Zhou, X Yin, Y Chen, Y Shi - Macromolecules, 2023 - ACS Publications
Water-soluble molecular bottlebrushes (MBBs) with various functions and tunable
morphologies have found promising application prospects in the biorelevant field. However …

Influence of the Norbornene Anchor Group in Ru-Mediated Ring-Opening Metathesis Polymerization: Synthesis of Linear Polymers

SJ Scannelli, A Paripati, JR Weaver, C Vu… - …, 2023 - ACS Publications
Ring-opening metathesis polymerization (ROMP) mediated by Grubbs' first-generation
catalyst [G1,(PCy3) 2 (Cl) 2RuCHPh] and Grubbs' third-generation catalyst [G3,(H2IMes)(Cl) …