Single‐atom catalysts (SACs) have become a prominent theme in heterogeneous catalysis,
not least because of the potential fundamental insight into active sites. The desired level of …

The phosphino‐phosphonium cations of the form [R3PPR′ 2]+ are labile and provide
access to the constituent Lewis acidic and Lewis basic fragments. This permits frustrated …

Kinetic profiles obtained from monitoring the solution-phase substitution chemistry of [Ru (η5-
indenyl)(NCPh)(PPh3) 2]+(1) by both electrospray ionization mass spectrometry and 31P …

The insertion of unsaturated organic molecules into a P− P bond of oligophosphorus
compounds has the potential to expand the organophosphorus and organometallic …

A focus on phosphinophosphination of apolar bonds by a structurally constrained P–P bonded
system - Chemical Science (RSC Publishing) DOI:10.1039/D4SC90251C Royal Society of …

(NHC)→ E coordination interactions are being explored in many chemical species, including
carbones and nitreones.(NHC)→ S interactions are rare, but increasing attention is being …

Heterolytic cleavage of homoatomic bonds is a challenge, as it requires separation of
opposite charges. Even highly strained homoatomic rings (eg, cyclopropane and …

By reaction of two equivalents of Me3Si− F− Al (ORF) 3 1 with an equimolar amount of
PPh2Cl, the salt [Ph2P− PPh2Cl]+[(RFO) 3Al− F− Al (ORF) 3]− 2 is prepared smoothly in …

Oxidative addition (OA) is an important elementary step in chemistry, but it has been studied
mainly in the context of transition-metal-catalyzed reactions and mainly with carbon–X …

Combination of a phosphinidene precursor, B (C6F5) 3 and 4-ethynyltoluene afforded the
FLP addition product, Et2N (C14H10) PC (Tol) CH (B (C6F5) 3) 2. Compound 2 reacted with …